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首页> 外文期刊>Optik: Zeitschrift fur Licht- und Elektronenoptik: = Journal for Light-and Electronoptic >Effect of annealing on optical and structural properties of ZnS/MnS and MnS/ZnS superlattices thin films for solar energy application
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Effect of annealing on optical and structural properties of ZnS/MnS and MnS/ZnS superlattices thin films for solar energy application

机译:退火对太阳能应用ZnS / MnS和MnS / ZnS超晶格薄膜的光学和结构性能的影响

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摘要

ZnS/MnS super lattice thin films were grown on glass substrates by Chemical Bath Deposition technique. Equimolar aqueous solutions of ZnCl_2:thiourea and MnCl_2·2H_2O:thiourea were taken separately. The substrates were placed vertically in the beakers containing the precursor described above, and the films are deposited at 85?C for an hour. The as deposited films are annealed at 200?C for about two hours. X-ray diffractometry method was used to obtain structural characterization. The UV-vis absorption spectrometry was employed to find the optical properties. The refractive-index, dielectric constant, optical conductivity, electrical conductivity and extinction coefficient were determined by various equations based on the data. The valence band and conduction band offset voltages for ZnS/MnS were determined as 0.7 eV and 0.1 eV respectively and for MnS/ZnS were 0.4 eV and 0.3 eV respectively. The band alignment of both superlattice was found to be as Type I.
机译:通过化学浴沉积技术在玻璃基板上生长ZnS / MnS超晶格薄膜。分别取等摩尔的ZnCl_2:硫脲和MnCl_2·2H_2O:硫脲的水溶液。将基板垂直放置在装有上述前体的烧杯中,然后将薄膜在85°C下沉积1小时。所沉积的薄膜在200℃下退火约两个小时。使用X射线衍射法获得结构表征。紫外可见吸收光谱法用于发现光学性质。折射率,介电常数,光导率,电导率和消光系数是根据数据通过各种方程式确定的。 ZnS / MnS的价带和导带偏移电压分别确定为0.7 eV和0.1 eV,而MnS / ZnS的价带和导带偏移电压分别为0.4 eV和0.3 eV。发现两个超晶格的能带对准为I型。

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