Synthesis and characterization of eta(5)-1,2,4-diazaphospholide complexes of ruthenium

Zheng WJ; Zhang GZ; Fan KN

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Synthesis and characterization of eta(5)-1,2,4-diazaphospholide complexes of ruthenium

机译：钌的eta（5）-1,2,4-二氮杂磷化物配合物的合成与表征

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Treatment of the 1,2,4-diazaphospholide anions [3,5tBu(2)dp](-) - (1) and [3,5-Ph(2)dp](-) (2) with [Cp*RuCl](4) affords the two complexes [(eta(5)-3,5-tBu(2)dp)RuCp*] (3) and [(eta(5)-3,5-Ph(2)dp)- RuCp*] (4) (dp = 1,2,4-diazapholide), which are the first examples of sandwich complexes derived from 1,2,4-diazaphospholide ligands. The X-ray crystal structure analysis of 3 reveals that the metal atom is T-bonded to the 1,2,4-diazaphospholide ligand. The bonding was rationalized by DFT calculations.

机译：用[Cp * RuCl]处理1,2,4-二氮杂磷阴离子[3,5tBu（2）dp]（-）-（1）和[3,5-Ph（2）dp]（-）（2） ]（4）提供两种络合物[（eta（5）-3,5-tBu（2）dp）RuCp *]（3）和[（eta（5）-3,5-Ph（2）dp）- RuCp *]（4）（dp = 1,2,4-二氮杂磷化物），它们是衍生自1,2,4-二氮杂磷配体的三明治复合物的第一个实例。 3的X射线晶体结构分析表明，金属原子与1，2，4-二氮杂磷配体成T键。通过DFT计算使结合合理化。

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《Organometallics》 |2006年第7期|共3页
作者
Zheng WJ; Zhang GZ; Fan KN;
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正文语种 eng
中图分类有机化学;
关键词
ELECTRONIC-STRUCTURE; PYRROLYL LIGANDS; SOLID-STATE; DENSITY; DERIVATIVES; PHOSPHORUS; HETEROCYCLES; 1; 2; 4-DIAZAPHOSPHOLES; STABILIZATION; CHEMISTRY;

机译：电子结构;吡咯烷酮;固态;密度;衍生物;磷;杂环;1;2;4-二氮杂磷;稳定化;化学;

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Synthesis and characterization of eta(5)-1,2,4-diazaphospholide complexes of ruthenium

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