Single and multiple insertion of carbon-carbon triple bonds into the palladium-aryl bond of cationic and neutral arylpalladium complexes with a 2,2 '-bipyridine ligand

Yagyu T.; Brookhart M.; Osakada K.

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Single and multiple insertion of carbon-carbon triple bonds into the palladium-aryl bond of cationic and neutral arylpalladium complexes with a 2,2 '-bipyridine ligand

机译：将碳-碳三键单次或多次插入具有2,2'-联吡啶配体的阳离子和中性芳基钯络合物的钯-芳基键中

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Dimethyl acetylenedicarboxylate reacts with PdI(C6H3Me2-3,5)(bpy) in the presence of AgBF4, causing rapid insertion of three acetylene molecules into the Pd-C bond to afford [Pd{C(CCOOMe-CZ=CZ-CZ=CZ)(Z)(C6H3Me2-3,5)}(byp)]BF4 (Z = COOMe), whereas a similar reaction without AgBF4 gives the product of a single insertion of the carbon-carbon triple bond, Pd(I)(CZ=CZC(6)H(3)Me(2)-3,5)(bpy). [References: 37]

机译：乙炔二甲酸二甲酯在AgBF4存在下与PdI（C6H3Me2-3,5）（bpy）反应，导致三个乙炔分子快速插入Pd-C键中，从而得到[Pd {C（CCOOMe-CZ = CZ-CZ = CZ ）（Z）（C6H3Me2-3,5）}（byp）] BF4（Z = COOMe），而没有AgBF4的类似反应给出了碳-碳三键单插入的产物Pd（I）（CZ = CZC（6）H（3）Me（2）-3,5）（bpy）。 [参考：37]

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《Organometallics》 |2000年第11期|共5页
作者
Yagyu T.; Brookhart M.; Osakada K.;
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正文语种 eng
中图分类有机化学;有机质材料;
关键词
Alpha-diimine catalysts; Organopalladium complexes; Oxidative-addition; Alternating copolymerization; Cyclopalladated compounds; Stepwise insertion; X-ray; Olefins; Monoxide; Ethylene;

机译：α-二亚胺催化剂;有机钯配合物;氧化加成;交替共聚;环钯化合物;逐步插入;X射线;烯烃;一氧化碳;乙烯;

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1. Single and multiple insertion of carbon-carbon triple bonds into the palladium-aryl bond of cationic and neutral arylpalladium complexes with a 2,2 '-bipyridine ligand [J] . Yagyu T., Brookhart M., Osakada K. Organometallics . 2000,第11期

机译：将碳-碳三键单次或多次插入具有2,2'-联吡啶配体的阳离子和中性芳基钯络合物的钯-芳基键中
2. Chemical properties of cationic phenylplatinum(II) complexes with a 2,2 '-bipyridine ligand. Insertion of CO and allene into the Pt-C bond and oxidative addition of MeI [J] . Yagyu T., Suzaki Y., Osakada K. Organometallics . 2002,第10期

机译：具有2,2'-联吡啶配体的阳离子苯基铂（II）配合物的化学性质。将CO和丙二烯插入Pt-C键和MeI的氧化加成
3. Single and Multiple Insertion of Alkynes into pd-Acyl and pd-Aryl Bonds in Cationic Palladium Complexes with Phosphine-Imine (P approx N) ligands [J] . K.Rajender Reddy, K.Surekha Gene-Hsiang Lee, Shie-Ming Peng, Organometallics . 2001,第26期

机译：带有膦亚胺（P约N）配体的阳离子钯络合物中炔烃单次或多次插入pd-酰基和pd-芳基键
4. Development of Robust Metal Complexes Using Immobilized Chiral 2,2’-Bipyridine Ligand for Enantioselective Reactions in Water [C] . Fangqiu LU, Taku KITANOSONO, Shu KOBAYASHI 日本化学会春季年会講演予稿集 . 2018

机译：使用固定的手性2,2'-硼吡啶配体进行鲁棒金属配合物的开发在水中对映选择性反应进行映选择性反应
5. Electronic structure investigations of multiple bonding between atoms: From metal-nitrogen triple bonds to metal-metal triple and quadruple bonds. [D] . English, Jason Blaine. 2002

机译：原子之间多重键的电子结构研究：从金属-氮三键到金属-金属三键和四键。
6. Cationic Gold(I) Diarylallenylidene Complexes: Bonding Features and Ligand Effects [O] . Diego Sorbelli, Dr. Laura Nunes dos Santos Comprido, Prof. Dr. Gerald Knizia, -1

机译：阳离子金（I）二芳基亚烯基络合物：键合特征和配体效应
7. Evidence for an Equilibrium between Neutral and Cationic Arylpalladium(II) Complexes in DMF. Mechanism of the Reduction of Cationic Arylpalladium(II) Complexes. [O] . Christian Amatore, Emmanuelle Carré, Anny Jutand, 1998

机译：DMF中中性和阳离子芳基钯（II）复合物之间平衡的证据。减少阳离子芳基钯（II）配合物的机理。

Single and multiple insertion of carbon-carbon triple bonds into the palladium-aryl bond of cationic and neutral arylpalladium complexes with a 2,2 '-bipyridine ligand

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