Cyclometalated cis-chelated bidentate n-heterocyclic carbene palladium complexes: Synthetic, structural, and catalytic studies

Liu Z; Zhang T; Shi M

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Cyclometalated cis-chelated bidentate n-heterocyclic carbene palladium complexes: Synthetic, structural, and catalytic studies

机译：环金属化的顺式螯合双齿正碳杂环卡宾钯配合物：合成，结构和催化研究

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Novel cyclometalated cis-chelated bidentate N-heterocyclic carbene palladium complexes derived from binaphthyl-2,2'-diamine (BINAM) have been successfully synthesized, and the cyclometalated cis-chelated bidentate NHC-palladium(II) complex 5a has been characterized by X-ray crystal structure diffraction. Moreover, we found that these novel NHC-palladium(II) complexes are quite effective in Suzuki-Miyaura coupling reactions and Friedel-Crafts reactions under mild conditions.

机译：已成功合成了衍生自联萘-2,2'-二胺（BINAM）的新型环金属化的顺式螯合双齿N-杂环卡宾钯配合物，并用X表征了环金属化的顺式螯合双齿NHC-钯（II）配合物5a -射线晶体结构衍射。此外，我们发现这些新颖的NHC-钯（II）配合物在温和条件下的Suzuki-Miyaura偶联反应和Friedel-Crafts反应中非常有效。

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《Organometallics》 |2008年第11期|共4页
作者
Liu Z; Zhang T; Shi M;
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正文语种 eng
中图分类有机化学;
关键词
INTRAMOLECULAR-COORDINATION COMPOUNDS; CROSS-COUPLING REACTIONS; BOND-FORMING REACTIONS; NITROGEN DONOR LIGAND; C-C; ORGANIC-SYNTHESIS; PINCER COMPLEXES; METAL-COMPLEXES; ARYL CHLORIDES; HOMOGENEOUS CATALYSIS;

机译：分子内配位化合物;交叉偶联反应;键合反应;氮掺杂剂配体;C-C;有机合成;针状配合物;金属络合物;芳族氯化物;均相催化;

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1. Cyclometalated cis-chelated bidentate n-heterocyclic carbene palladium complexes: Synthetic, structural, and catalytic studies [J] . Liu Z, Zhang T, Shi M Organometallics . 2008,第11期

机译：环金属化的顺式螯合双齿正碳杂环卡宾钯配合物：合成，结构和催化研究
2. Silver(I), mercury(II) and palladium(II) complexes of functionalized N-heterocyclic carbenes: Synthesis, structural studies and catalytic activity [J] . Liu Q.-X., Li H.-L., Zhao X.-J., Inorganica Chimica Acta . 2011,第1期

机译：功能化的N-杂环卡宾的银（I），汞（II）和钯（II）配合物：合成，结构研究和催化活性
3. Palladium(II) complexes of a bis-2-aminobiphenyl N-heterocyclic carbene: Synthesis, structural studies and catalytic activity [J] . Fliedel C, Maisse-Francois A, Bellemin-Laponnaz S Inorganica Chimica Acta . 2007,第1期

机译：双-2-氨基联苯N-杂环卡宾的钯（II）配合物：合成，结构研究和催化活性
4. Bidentate N-Heterocyclic Carbene Complexes of Group 6 Transition Metals:Synthesis, Structure, and Reactivity [C] . Kenichi Ogata, Yoshitaka Yamaguchi, Takashi Ito Symposium on Organometallic Chemistry . 2006

机译：二齿N-杂环卡宾络合物的第6组过渡金属：合成，结构和反应性
5. Synthetic, structural, spectroscopic, catalytic and mechanistic studies of palladium complexes with bidentate carbene ligands [D] . Subramanium, Sri Skandaraja 2011

机译：带有二齿卡宾配体的钯配合物的合成，结构，光谱，催化和机理研究
6. A Stable (Amino)(Phosphino)Carbene as bidentate ligand for Palladium and Nickel Complexes: Synthesis Structure and Catalytic Activity [O] . Emmanuelle Teuma, Céline Lyon-Saunier, Heinz Gornitzka, -1

机译：稳定的（氨基）（膦）碳作为钯和镍配合物的双齿配体：合成结构和催化活性
7. Synthesis and structural characterization of palladium(II) complexes of chiral bidentate N-heterocyclic carbene-quinoline ligands [O] . Erica L. Ingalls, G. Andrew Holtzen, Werner Kaminsky, 2017

机译：手性二齿N-杂环喹啉配体的钯（II）复合物的合成与结构表征

Cyclometalated cis-chelated bidentate n-heterocyclic carbene palladium complexes: Synthetic, structural, and catalytic studies

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