Methyl levamisolium triflate as a precursor to a chiral bifunctional N-heterocyclic carbene-thiolate ligand: Palladium(II) complexes

Cabeza JA; del Rio I; Sanchez-Vega MG; Suarez M

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Methyl levamisolium triflate as a precursor to a chiral bifunctional N-heterocyclic carbene-thiolate ligand: Palladium(II) complexes

机译：三氟甲磺酸左乙酰胺酸甲酯作为手性双官能N-杂环卡宾-硫醇盐配体的前体：钯（II）配合物

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Cationic palladium(H) complexes containing the chiral N-heterocyclic carbene (NHC) ligand l-ethylenethiolate-3-methyl-4-(R)-phenylimidazoline-2-ylidene have been prepared in one-pot reactions that involve the oxidative addition of the C-S bond of methyl levamisolium to [Pd(dba)(2)] (dba = dibenzylidene acetone). These reactions represent an easy entry into complexes having chiral NHC ligands.

机译：包含手性N-杂环卡宾（NHC）配体1-亚乙基硫酯-3-甲基-4-（R）-苯基咪唑啉-2-亚烷基的阳离子钯（H）配合物已通过一锅法制备，该反应涉及氧化加成甲基乙酰氨基的CS键与[Pd（dba）（2）]（dba =二亚苄基丙酮）。这些反应代表容易进入具有手性NHC配体的复合物。

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来源
《Organometallics》 |2006年第7期|共4页
作者
Cabeza JA; del Rio I; Sanchez-Vega MG; Suarez M;
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正文语种 eng
中图分类有机化学;
关键词
TRANSITION-METAL-COMPLEXES; S BOND-CLEAVAGE; ASYMMETRIC KETONE HYDROSILYLATION; OLEFIN METATHESIS; CRYSTAL-STRUCTURE; STABLE CARBENES; PLATINUM(II); CATALYSIS; HYDRODESULFURIZATION; COORDINATION;

机译：过渡金属络合物;键合键断裂;不对称酮酮的加氢硅烷基化;烯烃复分解;晶体结构;稳定的碳;铂（II）;催化;加氢脱硫;配位;

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1. Methyl levamisolium triflate as a precursor to a chiral bifunctional N-heterocyclic carbene-thiolate ligand: Palladium(II) complexes [J] . Cabeza JA, del Rio I, Sanchez-Vega MG, Organometallics . 2006,第7期

机译：三氟甲磺酸左乙酰胺酸甲酯作为手性双官能N-杂环卡宾-硫醇盐配体的前体：钯（II）配合物
2. N-Heterocyclic carbene (NHC) palladium(II) complexes bearing chiral oxazoline ligands and their catalytic activities in allylic alkylation reactions [J] . Serpil DENIZALTI, Hayati TURKMEN, Bekir CETINKAYA Turkish journal of chemistry . 2014,第5期

机译：带有手性恶唑啉配体的N-杂环卡宾（NHC）钯（II）配合物及其在烯丙基烷基化反应中的催化活性
3. N-Heterocyclic carbene (NHC) palladium(II) complexes bearing chiral oxazoline ligands and their catalytic activities in allylic alkylation reactions [J] . SERP?L DEN?ZALTI, HAYAT? TüRKMEN, BEK?R ?ET?NKAYA Turkish journal of chemistry . 2014,第5期

机译：带有手性恶唑啉配体的N-杂环卡宾（NHC）钯（II）配合物及其在烯丙基烷基化反应中的催化活性
4. Synthesis of Phenylpyridine Iridium(III) Complexes with N-Heterocyclic Carbene as Ancillary Ligands [C] . N H A Bain, N M Ali, Y Juahir International Fundamentum Science Symposium . 2019

机译：用N-杂环烷烃作为辅助配体的合成苯吡啶铱（III）配合物
5. I. Multicatalysis: Development of a Bismuth(III) triflate-catalyzed Nucleophilic addition/ Hydrofunctionalization Reaction in the Synthesis of Complex Heterocycles II. C--H Arylation of Arenes and Heteroarenes with Palladium-Carboxylate Catalysts: Identification of the Catalyst Resting State and the Crucial Role of Pivalate Ligand in Stabilization of the Catalyst III. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Importance of Phosphine Ligand for Basic Heteroarene Substrates IV. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Effect of the Properties of Basic Heteroarene Substrates on Direct Arylations. [D] . Tundel, Rachel E. 2011

机译：I.多催化作用：在复杂的杂环化合物的合成中三氟甲磺酸铋（III）催化的亲核加成/加氢官能化反应的发展。羰基钯催化剂对芳烃和杂芳烃的CH-H芳基化反应：催化剂静止状态的鉴定以及新戊酸酯配体在稳定催化剂中的关键作用III。羰基钯催化剂催化杂芳烃的CH芳基化：膦配体对基础杂芳烃基质的重要性IV。杂芳烃与钯-羧酸酯的CH芳基化：碱性杂芳烃底物性能对直接芳基化的影响。
6. Palladium(II) Complexes Containing Mixed Nitrogen-Sulphur Donor Ligands: Interaction of Pd(Methionine Methyl Ester)(H2O)22+ with Biorelevant Ligands [O] . Mohamed M. Shoukry, Sameya M. T. Ezzat 2014

机译：含混合氮硫供体配体的钯（II）配合物：Pd（蛋氨酸甲基酯）（H2O）2 2+与生物相关配体的相互作用
7. Synthesis and structural characterization of palladium(II) complexes of chiral bidentate N-heterocyclic carbene-quinoline ligands [O] . Erica L. Ingalls, G. Andrew Holtzen, Werner Kaminsky, 2017

机译：手性二齿N-杂环喹啉配体的钯（II）复合物的合成与结构表征
8. Novel Square Pyramidal Copper(II) Complexes of the Stereospecific Linear NSNNTetradentate Ligand N-((2-Pyridyl)methyl)-2-((2-Aminoethyl)thio) Acetamide (pygeH). The Crystal Structures of (Cu(pyge)X) (X = Br, N3) [R] . Toscano, P. J., Fordon, K. J., Macherone, D., 1990

机译：新型方形金字塔形铜（II）配合物的立体特异性线性NsNN四齿配体N - （（2-吡啶基）甲基）-2 - （（2-氨基乙基）硫代）乙酰胺（pygeH）。（Cu（pyge）X）（X = Br，N3）的晶体结构

Methyl levamisolium triflate as a precursor to a chiral bifunctional N-heterocyclic carbene-thiolate ligand: Palladium(II) complexes

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