Rational design of a chiral palladium(0) olefin complex of unprecedented stability

Grundl MA; Kennedy-Smith JJ; Trauner D

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Rational design of a chiral palladium(0) olefin complex of unprecedented stability

机译：前所未有的稳定性的手性钯（0）烯烃配合物的合理设计

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摘要

A chiral bidentate olefin ligand L with a 1,4a,5,8a-tetrahydro-naphthalene-2,6-dione framework has been designed, which forms a homoleptic palladium(0) complex L2Pd of unprecedented stability.

机译：设计了具有1,4a，5,8a-四氢萘-2,6-二酮骨架的手性双齿烯烃配体L，形成了前所未有的稳定性的均相钯（0）络合物L2Pd。

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《Organometallics》 |2005年第12期|共3页
作者
Grundl MA; Kennedy-Smith JJ; Trauner D;
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正文语种 eng
中图分类有机化学;
关键词
LIGANDS; REACTIVITY; NICKEL(II); BONDS; ELIMINATION; PLATINUM(0); MECHANISM; INSERTION; CRYSTAL; METHOXO;

机译：脂类;反应性;镍（II）;键;消除;铂（0）;机理;插入;晶体;甲氧基;

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1. Rational design of a chiral palladium(0) olefin complex of unprecedented stability [J] . Grundl MA, Kennedy-Smith JJ, Trauner D Organometallics . 2005,第12期

机译：前所未有的稳定性的手性钯（0）烯烃配合物的合理设计
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3. Diastereoselective and Enantioselective Synthesis of Barbiturate-Fused Spirotetrahydroquinolines via Chiral Palladium(0)/Ligand Complex Catalyzed [4+2] Cycloaddition of Vinyl Benzoxazinanones with Barbiturate-Based Olefins [J] . Zhao Hong-Wu, Feng Ning-Ning, Guo Jia-Ming, The Journal of Organic Chemistry . 2018,第16期

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4. Novel Chiral Pincer Palladium Complexes Bearing Pyrroloimidazolone Unit:Design,Preparation,and Synthetic Application [C] . Yasuhiro Uozumi Symposium on Organometallic Chemistry . 2003

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5. 1. Axially-chiral 7-membered N-heterocyclic carbenes: Synthesis and application to palladium-catalyzed intramolecular aerobic oxidation of olefins 2. Development of palladium-catalyzed aerobic oxidative olefin amination reactions [D] . Scarborough, Christopher C. 2008

机译：1.轴向手性7元N-杂环卡宾：烯烃的钯催化分子内需氧氧化的合成及应用2.钯催化需氧氧化烯烃胺化反应的发展
6. On the Configurational Stability of Chiral Heteroatom-Substituted D1Methylpalladium Complexes as Intermediates of Stille and Suzuki–Miyaura Cross-Coupling Reactions [O] . Petra Malova Krizkova, Friedrich Hammerschmidt -1

机译：关于Stille和Suzuki-Miyaura交叉偶联反应中间体的手性杂原子取代的D1甲基钯配合物的构型稳定性
7. Rational Design of a Chiral Palladium(0) Olefin Complex of Unprecedented Stability [O] . -1

机译：手性钯（0）烯烃复合物的理性设计，前所未有的稳定性
8. Reactions of Low-valent Metal Complexes with Fluorocarbons. Part 31. Bis(eta-cyclo-octa-1,5-diene)-platinum and -palladium, with Fluoro-Olefins. [R] . Green, M., Laguna, A., Spencer, J. L., 1976

机译：低价金属配合物与碳氟化合物的反应。部分31.双（η-环 - 辛-1,5-二烯） - 铂和 - 钯，含氟 - 烯烃。

Rational design of a chiral palladium(0) olefin complex of unprecedented stability

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