Unsymmetrically substituted iridium(III)-carbene complexes by a CH-activation process

Prinz M.; Herdtweck E.; Herrmann WA.; Grosche M.

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Unsymmetrically substituted iridium(III)-carbene complexes by a CH-activation process

机译：通过CH活化过程不对称取代的铱（III）-卡宾络合物

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The synthesis of the metalhydride Cp*(L')IrH+OTf- (L' = 1-(2-cyclohexenyl)-3-cyclohexylimidazolin-2-ylidene, OTf = OSO2CF3) is achieved by a cyclohexane to cyclohexene transformation at the N-heterocyclic carbene ligand based on a CH-activation/beta-hydrogen migration process at the Ir(III) center under mild conditions. The synthetic route to Cp*(L')IrH+OTf- and NMR spectroscopic and X-ray structural data are presented. [References: 23]

机译：金属氢化物Cp *（L'）IrH + OTf-（L'= 1-（2-环己烯基）-3-环己咪唑啉-2-亚烷基，OTf = OSO2CF3）的合成是通过在N处进行环己烷到环己烯的转化来实现的-杂环卡宾配体基于在Ir（III）中心在温和条件下的CH活化/β-氢迁移过程。给出了合成Cp *（L'）IrH + OTf-的合成路线以及NMR光谱和X射线结构数据。 [参考：23]

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《Organometallics》 |2000年第9期|共3页
作者
Prinz M.; Herdtweck E.; Herrmann WA.; Grosche M.;
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正文语种 eng
中图分类有机化学;有机质材料;
关键词
H bonds; Metal-complexes; Tricyclohexylphosphine; Dehydrogenation; Ruthenium; Carbenes; Ir(iii); Mild;

机译：H键;金属配合物;三环己基膦;脱氢;钌;卡宾;Ir（iii）;轻度;

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1. Unsymmetrically substituted iridium(III)-carbene complexes by a CH-activation process [J] . Prinz M., Herdtweck E., Herrmann WA., Organometallics . 2000,第9期

机译：通过CH活化过程不对称取代的铱（III）-卡宾络合物
2. Neutral iridium(III) complexes bearing BODIPY-substituted N-heterocyclic carbene (NHC) ligands: synthesis, photophysics, in vitro theranostic photodynamic therapy, and antimicrobial activity [J] . Liu Bingqing, Monro Susan, Jabed Mohammed A., Photochemical & photobiological sciences: the official journal of the European Photochemistry Association and the European Society for Photobiology . 2019,第10期

机译：中性铱（III）复合物轴承Bodipy-取代的N-杂环卡链（NHC）配体：合成，光学，体外的治疗光动力治疗和抗微生物活性
3. Theoretical Investigation of the Effect of N Substitution in CN and NN Heteroaromatic Ligands on the Photophysical Properties of Two Series of Iridium(III) Carbene Complexes [J] . Shang Xiaohong, Han Deming, Zhang Huiying, European journal of inorganic chemistry . 2016,第10期

机译：对CN和NN杂芳族配体中N取代对两种铱（III）碳配合物光物理性质影响的理论研究
4. Bifunctional Selective Hydrosilylation of Terminal Alkynes by Bis(carbene)Iridium(III)and Rhodium(III)Complexes [C] . Luis A.Oro Annual Saudi-Japan Symposium on Technology in Petroleum Refining and Petrochemicals . 2018

机译：双（卡宾烯）铱（III）和铑（III）配合物的末端炔烃的双官能选择性氢化硅烷化
5. I. Synthesis and reactivity of chiral iridium(III) and rhodium(III) complexes. II. Platinum-catalyzed iridium-methyl and iridium-phenyl bond formation [D] . Smith, Stuart Edward 2008

机译：I.手性铱（III）和铑（III）配合物的合成和反应性。二。铂催化的铱甲基和铱苯基键的形成
6. Luminescent ruffled iridium(iii) porphyrin complexes containing N-heterocyclic carbene ligands: structures spectroscopies and potent antitumor activities under dark and light irradiation conditions [O] . Tsz-Lung Lam, Ka-Chung Tong, Chen Yang, 2019

机译：含N-杂环卡宾配体的发光的荷叶铱（iii）卟啉配合物：在暗和光照射条件下的结构光谱学和有效的抗肿瘤活性
7. Iridium(I) and Iridium(III) Complexes Supported by a Diphenolate Imidazolyl-Carbene Ligand [O] . Weinberg David R., Hazari Nilay, Labinger Jay A., 2010

机译：二酚盐咪唑基-碳配体负载的铱（I）和铱（III）配合物

Unsymmetrically substituted iridium(III)-carbene complexes by a CH-activation process

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