Synthesis, chemical characterization, and molecular structures of Ag8Fe4(CO)(16)(dppm)(2) and Ag4Au4Fe4(CO)(16)(dppe)(2)

Albano VG.; Longoni G.; Monari M.; Paselli A.; Zacchini S.; Iapalucci MC.

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Synthesis, chemical characterization, and molecular structures of Ag8Fe4(CO)(16)(dppm)(2) and Ag4Au4Fe4(CO)(16)(dppe)(2)

机译：Ag8Fe4（CO）（16）（dppm）（2）和Ag4Au4Fe4（CO）（16）（dppe）（2）的合成，化学表征和分子结构

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The new Ag-8{Fe(CO)(4)}(4)(dppm)(2) and Ag4Au4{Fe(CO)(4)}(4)((PP)-P-boolean AND)(2) ((PP)-P-boolean AND = dppm, dppe) neutral cluster compounds have been isolated in good yields by condensation in CH3CN or THF of M-2((PP)-P-boolean AND)(2+) (M = Ag, Au) cations with [Ag-4{Fe(CO)(4)}(4)](4-) anions and characterized by IR, NMR, and microanalyses. The structure of both Ag-8{Fe(CO)(4)}(4)(dppm)(2) and Ag4Au4{Fe(CO)(4)}(4)(dppe)(2) has been determined by X-ray diffraction studies. The former represents a very rare example of a neutral Ag-Fe cluster containing phosphine as ancillary ligand for silver. [References: 26]

机译：新的Ag-8 {Fe（CO）（4）}（4）（dppm）（2）和Ag4Au4 {Fe（CO）（4）}（4）（（PP）-P-布尔AND）（2）（（PP）-P-布尔AND = dppm，dppe）通过在CH3CN或THF中缩合M-2（（PP）-P-布尔AND）（2+）（M =具有[Ag-4 {Fe（CO）（4）}（4）]（4-）阴离子的Ag，Au）阳离子，并通过IR，NMR和微量分析进行了表征。 Ag-8 {Fe（CO）（4）}（4）（dppm）（2）和Ag4Au4 {Fe（CO）（4）}（4）（dppe）（2）的结构均由X确定射线衍射研究。前者代表了一个非常罕见的中性Ag-Fe簇的例子，该簇含有磷化氢作为银的辅助配体。 [参考：26]

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《Organometallics》 |1998年第20期|共6页
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Albano VG.; Longoni G.; Monari M.; Paselli A.; Zacchini S.; Iapalucci MC.;
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中图分类有机化学;有机质材料;
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1. Synthesis, chemical characterization, and molecular structures of Ag8Fe4(CO)(16)(dppm)(2) and Ag4Au4Fe4(CO)(16)(dppe)(2) [J] . Albano VG., Longoni G., Monari M., Organometallics . 1998,第20期

机译：Ag8Fe4（CO）（16）（dppm）（2）和Ag4Au4Fe4（CO）（16）（dppe）（2）的合成，化学表征和分子结构
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Synthesis, chemical characterization, and molecular structures of Ag8Fe4(CO)(16)(dppm)(2) and Ag4Au4Fe4(CO)(16)(dppe)(2)

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