Amine Attack on the Carbonyl Ligands of the Protonated Dicyclopentadenyl-Bridged Diruthenium Complex [{(#eta#~5-C_5H_3)_2(SiMe_2)_2}Ru_2(CO)_4(#mu#-H)]~+

Maxim V. Ovchinnikov; Ilia A. Guzei; Robert J. Angelici

首页> 外文期刊>Organometallics >Amine Attack on the Carbonyl Ligands of the Protonated Dicyclopentadenyl-Bridged Diruthenium Complex [{(#eta#~5-C_5H_3)_2(SiMe_2)_2}Ru_2(CO)_4(#mu#-H)]~+

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Amine Attack on the Carbonyl Ligands of the Protonated Dicyclopentadenyl-Bridged Diruthenium Complex [{(#eta#~5-C_5H_3)_2(SiMe_2)_2}Ru_2(CO)_4(#mu#-H)]~+

机译：胺对质子化双环戊烯基-桥联钌络合物[{（＃eta＃〜5-C_5H_3）_2（SiMe_2）_2} Ru_2（CO）_4（＃mu＃-H）]〜+的羰基配体的攻击

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Complexes [{(#eta#~5-C_5H_3)_2(SiMe_2)_2}Ru_2(CO)_4(#mu#-H)]~+ (1H~+BF_4, 1D~+TfO~-), with a protonated Ru-Ru bond, were prepared by protonation of {(#eta#~5-C_5H_3)_2(SiMe_2)_2}Ru_2(CO)_4 (1) with HBF_4 centre dot Et_2O or CF_3SO_3D.

机译：具有质子化的复合物[{（＃eta＃〜5-C_5H_3）_2（SiMe_2）_2} Ru_2（CO）_4（＃mu＃-H）]〜+（1H〜+ BF_4，1D〜+ TfO〜-）通过用HBF_4中心点Et_2O或CF_3SO_3D质子化{{＃eta＃〜5-C_5H_3）_2（SiMe_2）_2} Ru_2（CO）_4（1）来制备Ru-Ru键。

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《Organometallics》 |2001年第4期|共6页
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Maxim V. Ovchinnikov; Ilia A. Guzei; Robert J. Angelici;
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中图分类有机化学;有机质材料;
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1. Amine Attack on the Carbonyl Ligands of the Protonated Dicyclopentadenyl-Bridged Diruthenium Complex [{(#eta#~5-C_5H_3)_2(SiMe_2)_2}Ru_2(CO)_4(#mu#-H)]~+ [J] . Maxim V. Ovchinnikov, Ilia A. Guzei, Robert J. Angelici Organometallics . 2001,第4期

机译：胺对质子化双环戊烯基-桥联钌络合物[{（＃eta＃〜5-C_5H_3）_2（SiMe_2）_2} Ru_2（CO）_4（＃mu＃-H）]〜+的羰基配体的攻击
2. Reactions of Diruthenium Tetrahydride Complex (#eta#~5-C_5Me_5)Ru(#mu#-H)_4Ru(#eta#~5-C_5Me_5) with Vinylsilanes: Formation of a #mu#-Silylene Complex via Successive Si-H and Si-C Bond Cleavage of Dimethylvinylsilane [J] . Toshiro Takao, masa-aki Amako, Hiroharu Suzuki Organometallics . 2001,第16期

机译：四氢化钌配合物（＃eta＃〜5-C_5Me_5）Ru（＃mu＃-H）_4Ru（＃eta＃〜5-C_5Me_5）与乙烯基硅烷的反应：通过连续的Si-H和二甲基乙烯基硅烷的Si-C键裂解
3. Dicyclopentadienyl zirconium and hafnium complexes with the bridged (dimethylsilanodiyl)dicyclopentadienyl [(SiMe_2)(#eta#~5-C_5H_4)_2]~(2-) ligand. X-ray molecular structure of [Zr{(SiMe_2)(#eta#~5-C_5H_4)_2}(CH_2Ph)]_2(#mu#-O) [J] . Tomas Cuenca, Pilar Gomez-Sal, Carlos Martin, Journal of Organometallic Chemistry . 1999,第1期

机译：二环戊二烯基锆和ha与桥连的（二甲基硅烷基二基）二环戊二烯基[（SiMe_2）（＃eta＃〜5-C_5H_4）_2]〜（2-）配体形成配合物。 [Zr {（SiMe_2）（＃eta＃〜5-C_5H_4）_2}（CH_2Ph）] _ 2（＃mu＃-O）的X射线分子结构
4. The Thermochemical Studies of Protonated Amine-Crown Ether Complexes: Extension of the Kinetic Method [C] . Michael Zickus, Sara Koepke, Kevin Chong, American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics . 2009

机译：质子化胺 - 冠醚配合物的热化学研究：动力学方法的延伸
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6. Several Novel N-Donor Tridentate Ligands Formed in Chemical Studies of New fac-Re(CO)3 Complexes Relevant to fac-99mTc(CO)3 Radiopharmaceuticals. Attack of a Terminal Amine on Coordinated Acetonitrile [O] . Theshini Perera, Patricia A. Marzilli, Frank R. Fronczek, -1

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7. Models for incomplete nucleophilic attack on a protonated carbonyl group and electron-deficient alkenes: salts and zwitterions from 1-dimethylamino-naphthalene-8-carbaldehyde [O] . Lari, A, Pitak, MB, Coles, SJ, 2012

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Amine Attack on the Carbonyl Ligands of the Protonated Dicyclopentadenyl-Bridged Diruthenium Complex [{(#eta#~5-C_5H_3)_2(SiMe_2)_2}Ru_2(CO)_4(#mu#-H)]~+

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