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High Temperature VARTM of Phenylethynyl Terminated Imide (PETI) Resins

机译:苯乙炔基末端酰亚胺(PETI)树脂的高温VARTM

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摘要

Fabrication of composite structures using vacuum assisted resin transfer molding (VARTM) is generally more affordable than conventional autoclave techniques. Recent efforts have focused on adapting VARTM for the fabrication of high temperature composites. Due to their low melt viscosity and long melt stability, certain phenylethynyl terminated imides (PETI) can be processed into composites using high temperature VARTM (HT-VARTM). However, one of the disadvantages of the current HT-VARTM resin systems has been the high porosity of the resultant composites. For aerospace applications a void fraction of less than 2% is desired. In the current study, two PETI resins, LARC~(TM) PETI-330 and LARC~(TM) PETI-8 have been used to fabricate test specimens using HT-VARTM. The resins were infused into carbon fiber preforms at 260°C and cured between 316°C and 371°C. Modifications to the thermal cycle used in the laminate fabrication have reduced the void content significantly (typically <= 3%) for carbon fiber biaxially woven fabric. Photomicrographs of the panels were taken and void contents were determined by acid digestion. For carbon fiber uniaxial fabric, void contents of less than 2% have been obtained using both PETI-8 and PETI-330. Mechanical properties of the panels were determined at both room and elevated temperatures. These include short beam shear and flexure tests. The results of this work are presented herein.
机译:与传统的高压釜技术相比,使用真空辅助树脂传递模塑(VARTM)制造复合结构通常更经济。最近的努力集中在使VARTM适应高温复合材料的制造上。由于它们的低熔体粘度和长熔体稳定性,可以使用高温VARTM(HT-VARTM)将某些苯乙炔基封端的酰亚胺(PETI)加工成复合材料。然而,当前HT-VARTM树脂体系的缺点之一是所得复合材料的高孔隙率。对于航空航天应用,希望空隙率小于2%。在当前的研究中,两种PETI树脂LARC〜PETI-330和LARC〜PETI-8已被用于使用HT-VARTM制作测试样品。将树脂在260°C下注入碳纤维预成型件中,并在316°C至371°C之间固化。对层压制品制造中使用的热循环的修改已显着降低了碳纤维双轴织造织物的空隙率(通常<= 3%)。拍摄板的显微照片,并通过酸消化确定空隙含量。对于碳纤维单轴织物,使用PETI-8和PETI-330均获得了小于2%的空隙率。在室温和高温下都测定了板的机械性能。这些包括短梁剪切和弯曲测试。本文介绍了这项工作的结果。

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