Real energies of ferricinium cation transfer from water to organo-aqueous solvents

Topolevz V.V.; Krishtalik L.I.

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Real energies of ferricinium cation transfer from water to organo-aqueous solvents

机译：铁阳离子的真实能量从水转移到有机溶剂

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The redox potentials of ferrocene-ferricinium couple are determined for five organo-aqueous systems with respect to a reversible chloride electrode in the same solvent. Combined with the literature data on real (and some chemical) transfer energies of chloride ion, the effective real energies of ferricinium trans- fer from water into organo-aqueous mixtures are determined. These values do not obey the Born equation. Most probably, this is due to the selective solvation of cation by water and of neutral ferrocene molecule by an organic component.

机译：对于在相同溶剂中的五个可逆氯化物电极，确定了五个有机水体系的二茂铁-二茂铁对的氧化还原电势。结合有关氯离子的有功（和某些化学）转移能的文献数据，确定了从水中转移到有机-水混合物中的铁有效有效能。这些值不符合Born方程。这很可能是由于水对阳离子的选择性溶剂化和有机成分对中性二茂铁分子的选择性溶剂化。

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《Russian journal of electrochemistry》 |2012年第9期|共8页
作者
Topolevz V.V.; Krishtalik L.I.;
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原文格式 PDF
正文语种 eng
中图分类电化学、电解、磁化学;
关键词
Born equation; Ferricinium; Organo-aqueous mixtures; Selective solvation; Solvation energy; Surface potential;

机译：伯恩方程;ric;有机混合物;选择性溶剂化;溶剂化能;表面势;

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1. Real energies of ferricinium cation transfer from water to organo-aqueous solvents [J] . Topolevz V.V., Krishtalik L.I. Russian journal of electrochemistry . 2012,第9期

机译：铁阳离子的真实能量从水转移到有机溶剂
2. Gibbs energies of transfer of alkali metal cations between mutually saturated water-solvent systems determined from extraction experiments with radiotracer Cs-137 [J] . Rais J, Okada T, Alexova J The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2006,第16期

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3. Gibbs Energies of Transfer of Cations from Water to Mixed Aqueous Organic Solvents [J] . C.Kalidas, Glenn Hefter, Yizhak Marcus Chemical Reviews . 2000,第3期

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4. Gibbs energies of transfer of chiral anions across the interface waterchiral organic solvent determined with the help of three-phase electrodes [C] . Fritz Scholz, Rubin Gulaboski Conference on Dynamics and Structure of the Liquid-Liquid Interface . 2005

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机译：吉布斯在相互饱和水溶液系统之间的碱金属阳离子转移的吉布斯能量，所述水溶液与辐射实验与放射性RACER 137CS测定
8. Solvent Effects on Intervalence Electron-Transfer Energies for Biferrocene Cations: Comparisons with Molecular Models of Solvent Reorganization [R] . McManis, G. E., Gochev, A., Nielson, R. M., 1989

机译：溶剂对二茂铁阳离子电子转移能的影响：与溶剂重组的分子模型比较

Real energies of ferricinium cation transfer from water to organo-aqueous solvents

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