Electrochemiluminescence of tri(2,2 '-bipyridine)ruthenium in aqueous solution on a gold-nanoparticle-modified glassy carbon electrode

Lv BQ; Ren AS; Luo Y; Yuan HY; Xiao D

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Electrochemiluminescence of tri(2,2 '-bipyridine)ruthenium in aqueous solution on a gold-nanoparticle-modified glassy carbon electrode

机译：金（纳米）修饰的玻碳电极上三（2,2'-联吡啶）钌在水溶液中的化学发光

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The electrochemical behavior of electrochemical deposition of Au nanoparticles onto a glassy carbon electrode (GCE) and its application for the electrocatalytic electrogenerated chemiluminescence (ECL) of Ru(bpy)(3)(2+) in an aqueous solution without coreaction are investigated in this report. The modification of GCE by Au nanoparticles results in excellent catalysis of the ECL of Ru(bpy)(3)(2+). The effects of various factors, such as potential scan range, the presence of nitrogen and oxygen, and the scan rate on Ru(bpy)(3)(2+). ECL peaks, were systematically studied. This article has provided insight into the design of an Au-nanoparticle-modified electrode for ECL, analytical and catalytic applications.

机译：本文研究了Au纳米粒子在玻璃碳电极（GCE）上的电化学沉积行为及其在Ru（bpy）（3）（2+）在无共作用的水溶液中的电催化化学发光（ECL）中的应用报告。金纳米粒子对GCE的修饰导致Ru（bpy）（3）（2+）的ECL极佳的催化作用。 Ru（bpy）（3）（2+）等各种因素的影响，例如潜在的扫描范围，氮和氧的存在以及扫描速率。对ECL峰进行了系统的研究。本文对用于ECL，分析和催化应用的金纳米粒子修饰电极的设计提供了见解。

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来源
《Russian journal of electrochemistry》 |2008年第9期|共5页
作者
Lv BQ; Ren AS; Luo Y; Yuan HY; Xiao D;
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正文语种 eng
中图分类电化学、电解、磁化学;
关键词
electrogenerated chemiluminescence (ECL); Au nanoparticles; modified electrode; electrocatalytic; HYDROGEN-PEROXIDE; NANO-AU; CYTOCHROME-C; CHEMILUMINESCENCE; IMMOBILIZATION; ADSORPTION; BIOSENSOR; GLUCOSE; ACID;

机译：电生化学发光（ACL）;金纳米颗粒;修饰电极;电催化;氢过氧化物;纳米金;细胞色素C;化学发光;固定化;吸附;生物传感器;葡萄糖;酸;

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1. Electrochemiluminescence of tri(2,2 '-bipyridine)ruthenium in aqueous solution on a gold-nanoparticle-modified glassy carbon electrode [J] . Lv BQ, Ren AS, Luo Y, Russian journal of electrochemistry . 2008,第9期

机译：金（纳米）修饰的玻碳电极上三（2,2'-联吡啶）钌在水溶液中的化学发光
2. Electrochemistry and electrochemiluminescence of stable tris(2,2'-bipyridyl)ruthenium(II) monolayer assembled on benzene sulfonic acid modified glassy carbon electrode [J] . Haiyan Wang, Guobao Xu, Shaojun Dong Talanta: The International Journal of Pure and Applied Analytical Chemistry . 2001,第1期

机译：苯磺酸修饰的玻碳电极上稳定的三（2,2'-联吡啶基）钌（II）单层的电化学和电致发光
3. Quenching of the Electrochemiluminescence of Tris(2,2'-bipyridine)ruthenium(II)/Tri-n-propylamine by Pristine Carbon Nanotube and Its Application to Quantitative Detection of DNA [J] . Xiaofeng Tang, Dan Zhao, Jinchao He, Analytical chemistry . 2013,第3期

机译：碳纳米管对三（2,2'-联吡啶）钌（II）/三正丙胺的电化学发光猝灭及其在DNA定量检测中的应用
4. Study of the electrochemiluminescence based on the reaction of allopurinol with Tris (2,2'-bipyridine) ruthenium (II) [C] . Yuwu Chi, JunLin Xie, Guonan Chen Sino-France Workshop on Surface Electrochemistry of Molecules of Biological Interest and Biosensor Application . 2001

机译：基于Allopurinol与Tris（2,2'-硼烷）钌（II）的反应研究电化学发光
5. I. THE ELECTROCHEMISTRY OF NITRIC OXIDE AND A NITROUS ACID AT A MERCURY ELECTRODE IN AQUEOUS SOLUTIONS. II. ELECTROCHEMISTRY AND HYDROLYSIS KINETICS OF THE 2,2'-BIPYRIDINE COMPLEXES OF IRON(III) AND IRON(II); ELECTROCHEMICAL KINETIC PARAMETERS FOR SEVERAL IRON COMPLEXES. III. PROTON NUCLEAR MAGNETIC RESONANCE STUDIES OF URANIUM(IV)-ETHYLENE DIAMINETETRAACETIC ACID COMPLEXES IN AQUEOUS (DEUTERIUM-OXIDE) SOLUTIONS. [D] . EHMAN, DEWAYNE LEE. 1969

机译：I.水溶液中汞电极上一氧化二氮和亚硝酸的电化学二。铁（III）和铁（II）的2,2'-联吡啶络合物的电化学和水解动力学；多种铁络合物的电化学动力学参数。三，铀（IV）-水溶液（氧化氘）中铀（IV）-乙撑双氨基乙酸复合物的质子核磁共振研究
6. Dithiooxamide Modified Glassy Carbon Electrode for the Studies of Non-Aqueous Media: Electrochemical Behaviors of Quercetin on the Electrode Surface [O] . Ayşen Demir Mülazımoğlu, Ecir Yılmaz, İbrahim Ender Mülazımoğlu 2012

机译：用于非水介质的二硫代草酰胺修饰的玻碳电极：槲皮素在电极表面的电化学行为
7. Study of the Redox Properties of Singlet and Triplet Tris(2,2′-bipyridine)ruthenium(II) (Ru(bpy)32+) in Aqueous Solution by Full Quantum and Mixed Quantum/Classical Molecular Dynamics Simulations [O] . Polydefkis Diamantis, Jérôme Florian Gonthier, Ivano Tavernelli, 2014

机译：用全量子和混合量子/经典分子动力学模拟水溶液中单态和三重素三（2,2'-硼吡啶）钌（II）（Ru（BPY）3 2+）的氧化还原性能
8. Ultrafast excited state dynamics of tris-(2,2'-bipyridine) Ruthenium (II) [R] . Yeh, A. T. W. 2000

机译：三 - （2,2'-联吡啶）钌（II）的超快激发态动力学

Electrochemiluminescence of tri(2,2 '-bipyridine)ruthenium in aqueous solution on a gold-nanoparticle-modified glassy carbon electrode

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