The nature of ionic conduction of phases based on calcium thioytterbiate

Ananchenko BA; Kalinina LA; Ushakova YN; Fominykh EG; Koshurnikova EV

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The nature of ionic conduction of phases based on calcium thioytterbiate

机译：基于硫代二水合钙的相的离子传导性质

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The CaYb2S4 compound and the phases based on it are fabricated. The ranges of solid solutions of CaS and Yb2S3 in calcium thioytterbiate are determined using the methods of x-ray diffraction analysis and conductometry. Average ionic, electronic, cationic, and anionic transport numbers and the coefficients of self-diffusion and diffusion of majority carrier in the Yb2S3 solid solution based on CaYb2S4 are determined by the modified emf method, the polarization Hebb-Wagner method, and potentiostatic chronoammetry. To discuss the mechanism of ionic transfer, the data on the pycnometric and X-ray densities are compared.

机译：制备了CaYb2S4化合物及其相。 CaS和Yb2S3在硫代乙二酸钙中的固溶范围是使用X射线衍射分析和电导法确定的。基于改进的电动势法，极化赫布-瓦格纳法和恒电位计时法，确定了基于CaYb2S4的Yb2S3固溶体中平均离子，电子，阳离子和阴离子的迁移数以及多数载流子的自扩散和扩散系数。为了讨论离子转移的机理，比较了比重瓶和X射线密度的数据。

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来源
《Russian journal of electrochemistry》 |2009年第6期|共9页
作者
Ananchenko BA; Kalinina LA; Ushakova YN; Fominykh EG; Koshurnikova EV;
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正文语种 eng
中图分类电化学、电解、磁化学;
关键词
solid electrolytes; sulfide-ionic conduction conductometry; diffusion; coefficients; the emf method; mechanism of defect formation;

机译：固体电解质硫化物离子传导电导法扩散系数电动势法缺陷形成机理;

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机译：基于硫代二水合钙的相的离子传导性质
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The nature of ionic conduction of phases based on calcium thioytterbiate

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