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Copper and nickel ion removal from synthesized process water using BSA-coated bubbles

机译:使用BSA涂层的气泡从合成工艺水中去除铜和镍离子

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Biosorption of a ternary system containing copper, nickel and calcium ions was conducted to examine the ability of air-filled emulsions (AFE) to remove heavy metal ions from a synthetic process water. AFE is a novel colloidal material containing fine air bubbles encapsulated by a thin film of cysteine-rich protein. AFE introduces a high interfacial surface area between metal ions and extractant. Impact of different experimental conditions such as calcium ion concentration, AFE dosage and final solution pH on metal ion uptake was explored. Calcium ions exhibited an adverse effect on copper removal, which reduced by 70% due to both higher affinities of active binding sites for calcium ion compared to that of copper and nickel ions and bridging flocculation of microbubbles occurred in the solution. The results acquired from potentiometric titration showed the presence of three functional groups on the surface of bubbles (carboxylic, thiol and amine groups), the carboxylic group being the most abundant. (C) 2015 Elsevier B.V. All rights reserved.
机译:进行了包含铜,镍和钙离子的三元系统的生物吸附,以研究充气乳液(AFE)从合成工艺用水中去除重金属离子的能力。 AFE是一种新型胶体材料,其中包含被富含半胱氨酸的蛋白质薄膜包裹的细小气泡。 AFE在金属离子和萃取剂之间引入了高界面表面积。探索了钙离子浓度,AFE剂量和最终溶液pH等不同实验条件对金属离子吸收的影响。钙离子对铜的去除表现出不利影响,与铜和镍离子相比,由于钙离子的活性结合位点的亲和力更高,并且溶液中发生了微气泡的桥接絮凝,钙去除率降低了70%。从电位滴定法获得的结果表明,气泡表面上存在三个官能团(羧基,巯基和胺基),其中羧基最丰富。 (C)2015 Elsevier B.V.保留所有权利。

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