首页> 外文期刊>Ceramic Engineering and Science Proceedings >THE EFFECTS OF β-Si_3N_4 SEEDING AND α-Si_3N_4 POWDER SIZE ON THE DEVELOPMENT OF POROUS β-Si_3N_4 CERAMICS
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THE EFFECTS OF β-Si_3N_4 SEEDING AND α-Si_3N_4 POWDER SIZE ON THE DEVELOPMENT OF POROUS β-Si_3N_4 CERAMICS

机译:β-Si_3N_4粉末和α-Si_3N_4粉末尺寸对多孔β-Si_3N_4陶瓷发展的影响

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摘要

Porous silicon nitride (Si_3N_4) ceramics have significant potential in a number of engineering applications due to their potential for favorable mechanical properties, even with moderately high porosities. In the present work two methods of microstructural control were assessed; (i) seeding with β-Si_3N_4 grains and (ii) varying theα-Si_3N_4 starting powder size. The aim of this work was to develop a ceramic with an improved microstructure, resulting in increased strength. The β-Si_3N_4 seed grains were prepared 'in-house' using a simple, moderately low-temperature processing approach. A series of nominally bi-modal (X-Si_3N_4 powder mixtures were also examined, using various ratios of powders with particle sizes of approximately 0.3 and 1.0 μm. It was demonstrated that the β-Si_3N_4 aspect ratio was predominantly influenced by the amount of coarse α-Si_3N_4 powder in the starting mixture, rather than the amount of β-Si_3N_4 seed grains. The highest aspect ratios (up to -12:1) were obtained when using 100% coarse α-Si_3N_4, as the a- to β-Si_3N_4 transformation period is prolonged, The strength was also slightly increased with a higher coarse α-Si_3N_4 fraction in the starting mixture. In this instance, seeding was shown to provide a small benefit, with the highest strengths (up to ~350 MPa) observed for samples prepared with 0 5 and 1 wt.% β-Si_3N_4 seed crystals.
机译:氮化硅(Si_3N_4)多孔陶瓷由于具有良好的机械性能(即使具有适度的高孔隙率)的潜力,因此在许多工程应用中也具有巨大的潜力。在目前的工作中,评估了两种微结构控制方法; (i)植入β-Si_3N_4晶粒,以及(ii)改变α-Si_3N_4起始粉末的大小。这项工作的目的是开发一种具有改善的微观结构,从而提高强度的陶瓷。 β-Si_3N_4籽粒使用简单,适度的低温加工方法“内部”制备。还检查了一系列标称双峰(X-Si_3N_4粉末混合物),使用各种比例的粒径分别为0.3和1.0μm的粉末。证明了β-Si_3N_4长径比主要受粗颗粒量的影响初始混合物中使用的是α-Si_3N_4粉末,而不是β-Si_3N_4籽粒的数量,当使用100%粗α-Si_3N_4作为α-至β-时,可获得最大的纵横比(最高-12:1)。 Si_3N_4的转变期延长,初始混合物中较高的粗α-Si_3N_4分数也使强度略有增加,在这种情况下,显示出晶种提供的好处很小,观察到的强度最高(最高〜350 MPa)。对于使用0 5和1 wt。%β-Si_3N_4籽晶制备的样品。

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