Emission switching of ferrocenyl Schiff bases and a representative ruthenium complex in alkaline DMSO: Absorption, electrochemical and microstructural studies

Mishra L; Dubey SK

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Emission switching of ferrocenyl Schiff bases and a representative ruthenium complex in alkaline DMSO: Absorption, electrochemical and microstructural studies

机译：二茂铁基席夫碱和有代表性的钌配合物在碱性DMSO中的发射转换：吸收，电化学和微结构研究

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N,N'-Bis(4-ferrocenyl)-p-phenylene/octamethylene-diimines (L-1/L-2) and a representative Ru(II) complex [Ru(DMSO)(2)Cl2L1]center dot 2H(2)O were prepared and characterized which showed many fold enhancement in their luminescence in alkaline dimethylsulfoxide (DMSO) solution. Spectral and electrochemical properties of these compounds have been studied. Microstructure (SEM) of L-1 and its complex showed single-phase porous material of crystal size similar to 1 mu m. (C) 2006 Elsevier B.V. All rights reserved.

机译：N，N'-双（4-二茂铁基）-对亚苯基/八亚甲基-二亚胺（L-1 / L-2）和代表性的Ru（II）络合物[Ru（DMSO）（2）Cl2L1]中心点2H（制备并表征了2）O，其在碱性二甲基亚砜（DMSO）溶液中的发光显示出许多倍的增强。已经研究了这些化合物的光谱和电化学性质。 L-1及其配合物的微观结构（SEM）显示晶体尺寸类似于1μm的单相多孔材料。（C）2006 Elsevier B.V.保留所有权利。

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《Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy》 |2007年第2期|共5页
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Mishra L; Dubey SK;
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正文语种 eng
中图分类分析化学;
关键词
ferrocenyl Schiff bases; emission switching; absorption spectrum; scanning electron micrographs; NONLINEAR-OPTICAL PROPERTIES; COORDINATION POLYMERS; NLO;

机译：二茂铁基席夫碱;发射转换;吸收光谱;扫描电镜;非线性光学性能;配位聚合物;NLO;

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1. Emission switching of ferrocenyl Schiff bases and a representative ruthenium complex in alkaline DMSO: Absorption, electrochemical and microstructural studies [J] . Mishra L, Dubey SK Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2007,第2期

机译：二茂铁基席夫碱和有代表性的钌配合物在碱性DMSO中的发射转换：吸收，电化学和微结构研究
2. Electrochemical studies of a series of antimetastatic mono- and di-ruthenium complexes [Na][trans-(RuCl4)-Cl-III(DMSO)(L)] and [Na](2)[{trans-(RuCl4)-Cl-III(DMSO)}(2)(mu-L)] (L = N-donor heterocyclic bridging ligand) [J] . Ravera M, Gabano E, Baracco S, Inorganica Chimica Acta . 2008,第9a10期

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3. Synthesis, Characterization, and Electrochemical Study of Tetradentate Ruthenium-Schiff Base Complexes: Dioxygen Activation with a Cytochrome P450 Model Using 1- or 2-Methylimidazole as Axial Bases [J] . AliOurari, MostefaKhelafi, DjouhraAggoun, Advances in physical chemistry . 2011,第4期

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4. A Novel Poly(ferrocenyl-Schiff base) and Its Charge Transfer Complex with Iodine [C] . Guoxuan Xiong, Haiqing Huang, Chuo Yang International Conference on Manufacturing Science and Engineering . 2009

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5. Organometallic chemistry of eta(6)-aromatic-cyclic-hydrocarbon manganese tricarbonyl complexes and electrochemical study of (arene)Cr(CO)(3) complexes having a pendent ferrocenyl switch. [D] . Yeung, Lee Kon. 1998

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6. Electrochemical behavior structural morphological Calf Thymus-DNA interaction and in-vitro antimicrobial studies of synthesized Schiff base transition metal complexes [O] . A. Palanimurugan, A. Dhanalakshmi, P. Selvapandian, 2019

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7. Tuning of Redox Potentials for the Design of Ruthenium Anticancer Drugs - an Electrochemical Study of trans-RuCl4L(DMSO)- and trans-RuCl4L2- Complexes, Where L = Imidazole, 1, 2, 4-Triazole, Indazole [O] . -1

机译：调整氧化钌抗癌药物设计的氧化还原电位 - 反式ruCl4L（DMSO） - 及反式ruCl4L2-配合物的电化学研究，其中L =咪唑，1,2,4-三唑，吲唑

Emission switching of ferrocenyl Schiff bases and a representative ruthenium complex in alkaline DMSO: Absorption, electrochemical and microstructural studies

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