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首页> 外文期刊>Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy >Synthesis and spectroscopic studies of copper(II) and nickel(II) complexes containing hydrazonic ligands and heterocyclic coligand
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Synthesis and spectroscopic studies of copper(II) and nickel(II) complexes containing hydrazonic ligands and heterocyclic coligand

机译:含肼基配体和杂环大肠菌群的铜(II)和镍(II)配合物的合成和光谱研究

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Two types of copper(II) and nickel(II) complexes derived from benzophenone anthranoylhydrazone (L-1), 2-acetonaftanone anthranoylhydrazone (L-2), 4-phenylacetonaftonone anthranoylhydrazone (LA benzophenone salicyoylhydrazone (L-4), 2-acetonaftanon salicyoylhydrazone (L-5), 4-phenylacetonaftanon salicyoylhydrazone (L-6) and bidentate heterocyclic base [1,10-phenanthroline (phen)] with general stoichiometry [ML2] and [ML(phen)]Cl have been synthesized and characterized by elemental analysis, infrared spectra, UV-vis electronic absorption spectra and magnetic susceptibility measurements. The effect of varying pH and solvent on the absorption behavior of both ligands and complexes have been investigated. According to the IR spectra, the ligands act as monobasic bidentate and coordination takes place in the enol tautomeric form. (c) 2005 Elsevier B.V. All rights reserved.
机译:分别由二苯甲酮蒽酰基hydr(L-1),2-丙酮af酮蒽酰基yl(L-2),4-苯基丙酮af酮蒽酰基hydr(LA二苯甲酮水杨酰hydr(L-4),2-丙酮af酮合成了水杨酰hydr(L-5),4-苯基丙酮酰水杨酰hydr(L-6)和具有化学计量比为[ML2]和[ML(phen)] Cl的双齿杂环碱[1,10-菲咯啉(phen)]。元素分析,红外光谱,紫外可见电子吸收光谱和磁化率测量;研究了pH和溶剂的变化对配体和配合物吸收行为的影响;根据红外光谱,配体充当了二元双齿和(c)2005 Elsevier BV保留所有权利。

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