Organocatalytic Conjugate Addition of Azide Ion to alpha,beta-Unsaturated Aldehydes

Sung-Gon Kim; Tae-Ho Park

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Organocatalytic Conjugate Addition of Azide Ion to alpha,beta-Unsaturated Aldehydes

机译：有机催化共轭叠氮化物离子到α，β-不饱和醛

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摘要

An efficient and simple amine-catatalyzed azide conjugate addition to alpha,beta-unsaturated aldehydes has been developed.In the presence of a catalytic amount of tertiary amine with a 1:1 mixture of NaN3 and 37% HCl in CH2Cl2,alpha,beta-unsaturated aldehydes provided beta-azido aldehydes,which could be transformed into 1,3-amino alcohols.

机译：已开发出一种有效且简单的胺催化叠氮化物共轭物，可将α，β-不饱和醛添加到催化中。在催化量的叔胺与NaN3和37％HCl的1：1混合物在CH2Cl2，α，β-不饱和醛提供了β-叠氮基醛，可以将其转化为1,3-氨基醇。

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《Synthetic Communications》 |2007年第6期|共9页
作者
Sung-Gon Kim; Tae-Ho Park;
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正文语种 eng
中图分类有机化学;
关键词
1; 3-amino alcohol; aza-Michael reaction; conjugate addition; organo-catalyst;

机译：1;3-氨基醇;氮杂-迈克尔反应;共轭加成;有机催化剂;

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专利

1. Organocatalytic Conjugate Addition of Azide Ion to alpha,beta-Unsaturated Aldehydes [J] . Sung-Gon Kim, Tae-Ho Park Synthetic Communications . 2007,第4a6期

机译：有机催化共轭叠氮化物离子到α，β-不饱和醛
2. Solvent-free Organocatalytic Asymmetric Conjugate Addition of Thiols to alpha,beta-Unsaturated Aldehydes [J] . Takeru Ishino, Takeshi Oriyama Chemistry Letters . 2007,第4期

机译：无溶剂有机催化不对称共轭加成硫醇到α，β-不饱和醛
3. Organocatalytic and direct asymmetric vinylogous Michael addition of alpha,alpha-dicyanoolefins to alpha,beta-unsaturated aldehydes [J] . Xie JW, Yue L, Xue D, Chemical Communications . 2006,第14期

机译：α，α-二氰基烯烃向α，β-不饱和醛的有机催化和直接不对称乙烯基迈克尔加成
4. Mass Spectrometric Characterization of Covalent Modification of Human Serum Albumin by alpha,beta-Unsaturated Aldehydes [C] . Qingyuan Liu, Scott Gronert ASMS Conference on Mass Spectrometry and Allied Topics . 2008

机译：α，β-不饱和醛类人血清白蛋白的共价修饰的质谱表征
5. Part I. Asymmetric organocatalysis: (1) Direct enantioselective organocatalytic hydroxymethylation of aldehydes catalyzed by alpha,alpha-diphenylprolinol trimethylsilyl ether: Application in the formal synthesis of (-)-Rasfonin; (2) Synthesis of a novel bicyclic secondary amine organocatalyst: Application to the direct enantioselective organocatalytic hydroxymethylation of aldehydes. Part II. Asymmetric synthesis of bicyclic analogues of the anti-osteoporotic drug risedronate. [D] . Miller, John Robert. 2010

机译：第一部分，不对称有机催化：（1）α，α-二苯基脯氨醇三甲基甲硅烷基醚催化的醛的直接对映选择性有机催化羟甲基化：在（-）-Rasfonin的正式合成中的应用；（2）新型双环仲胺有机催化剂的合成：应用于醛的直接对映选择性有机催化羟甲基化。第二部分抗骨质疏松药物Risedronate的双环类似物的不对称合成。
6. Organocatalytic Asymmetric Conjugate Addition of Aldehydes to Maleimides and Nitroalkenes in Deep Eutectic Solvents [O] . Alejandro Torregrosa-Chinillach, Alba Sánchez-Laó, Elisa Santagostino, 2019

机译：深共晶溶剂中醛向顺丁烯二酰亚胺和硝基烯烃的有机催化不对称共轭加成反应
7. Conjugate Additions of Grignard Reagents to alpha, beta-Unsaturated Esters. XV. Reactions with Octa-2,4,6-trienoic Ester. General Discussion of the Conjugate Addition Reaction. [O] . Steffen Jacobsen, Aage Jart, Ture Kindt-Larsen, 1963

机译：将GRIGNARD试剂的共轭添加至α，β-不饱和酯。 XV。用Octa-2,4,6-三烯酯的反应。缀合物添加反应的一般讨论。

Organocatalytic Conjugate Addition of Azide Ion to alpha,beta-Unsaturated Aldehydes

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