Asymmetric allylation of aldimines with indium and (+)-cinchonine

Han RB; Choi SH; Son KI; Jun YM; Lee BM; Kim BH

首页> 外文期刊>Synthetic Communications >Asymmetric allylation of aldimines with indium and (+)-cinchonine

【24h】

Asymmetric allylation of aldimines with indium and (+)-cinchonine

机译：醛亚胺与铟和（+）-辛可宁的不对称烯丙基化

获取原文

获取原文并翻译 | 示例

获取外文期刊封面封底 >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

By applying indium and allyl bromide, aldimines were converted into homoallyl amines with excellent yields. The addition of (+)-cinchonine to the reaction mixture yielded enantioselective allylation with 22-44% ee.

机译：通过施加铟和烯丙基溴，将醛亚胺以优异的产率转化为均烯丙基胺。向反应混合物中添加（+）-辛可宁产生对映体选择性烯丙基化，ee为22-44％。

著录项

来源
《Synthetic Communications》 |2005年第12期|共9页
作者
Han RB; Choi SH; Son KI; Jun YM; Lee BM; Kim BH;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
enantioselective allylation; indium; aldimines; homoallylamines; chiral ligand; MEDIATED ALLYLATION; AQUEOUS-MEDIA; DIASTEREOSELECTIVE ALLYLATION; ORGANOMETALLIC REACTIONS; HOMOALLYLIC AMINES; ORGANIC-SYNTHESIS; BARBIER-TYPE; IMINES; REAGENTS; ALDEHYDES;

机译：对映选择性烯丙基化;铟;亚胺次胺;高烯丙胺;手性配体;介导的烯丙基化;水介质;非对映选择性烯丙基化;有机金属反应;全烯丙基胺;有机合成;阻隔型;亚胺;试剂;醛;

相似文献

外文文献
中文文献
专利

1. Asymmetric allylation of aldimines with indium and (+)-cinchonine [J] . Han RB, Choi SH, Son KI, Synthetic Communications . 2005,第12期

机译：醛亚胺与铟和（+）-辛可宁的不对称烯丙基化
2. Asymmetric Activation of tropos 2,2'-Biphenol with Cinchonine Generates an Effective Catalyst for the Asymmetric Strecker Reaction of N-Tosyl-Protected Aldimines and Ketoimines [J] . Jun Wang, Xiaolei Hu, Jun Jiang Angewandte Chemie . 2007,第44期

机译：辛可宁对硝基2,2'-联苯酚的不对称活化产生了一个有效的催化剂，用于N-甲苯磺酰基保护的亚胺和酮亚胺的不对称Strecker反应
3. Indium triflate-catalyzed allylation reactions of N-sulfonyl aldimines or N-alkoxycarbonylamino p-tolylsulfones with allyltrimethylsilane: Synthesis of protected homoallylic amines [J] . Thirupathi P., Kim S.S. Tetrahedron . 2010,第45期

机译：三氟甲磺酸铟催化N-磺酰基醛亚胺或N-烷氧基羰基氨基对甲苯砜与烯丙基三甲基硅烷的烯丙基化反应：受保护的均烯丙基胺的合成
4. Synthesis of Nitrogen Heterocycles via Amphiphilic Allylation of Aldimine [C] . Katsumi Tohyama, Daisuke Nojiri, Masanari Kimura Symposium on Organometallic Chemistry . 2008

机译：通过醛胺的两亲烯丙基合成氮杂杂环
5. The tandem catalytic asymmetric allene diboration/imine allylation and the asymmetric transition-metal-catalyzed conjugate allylation of activated enones. [D] . Sieber, Joshua Daniel. 2008

机译：活化烯酮的串联催化不对称丙二烯二硼化/亚胺烯丙基化和不对称过渡金属催化的共轭烯丙基化。
6. Asymmetric Synthesis of Aminochromanes via Intramolecular Indium-Mediated Allylation of Chiral Hydrazones [O] . Debasis Samanta, Robert B. Kargbo, Gregory R. Cook -1

机译：经手性腙分子内铟介导的烯丙基化氨基苯并二氢吡喃的不对称合成
7. Indium-Mediated Asymmetric Barbier-Type Allylation of Aldimines in Alcoholic Solvents: Synthesis of Optically Active Homoallylic Amines [O] . -1

机译：铟介导的含酒精溶剂中醛胺的非对称倒钩型烯丙基：光学活性官胺的合成

Asymmetric allylation of aldimines with indium and (+)-cinchonine

摘要

著录项

相似文献

相关主题

期刊订阅