Synthesis of (R)-selegiline via hydrolytic kinetic resolution

Kondekar N.B.; Kumar P.

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Synthesis of (R)-selegiline via hydrolytic kinetic resolution

机译：水解动力学拆分合成（R）-司来吉兰

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摘要

A short and enantioselective formal synthesis of (R)-selegiline has been achieved using Jacobsen's hydrolytic kinetic resolution (HKR) of phenyl propylene oxide.

机译：（R）-司来吉兰的短而对映选择性的形式合成已使用Jacobsen的苯基环氧丙烷的水解动力学拆分（HKR）实现。

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《Synthetic Communications》 |2011年第9期|共8页
作者
Kondekar N.B.; Kumar P.;
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正文语种 eng
中图分类有机化学;
关键词
Cobalt-based chiral salen complex; hydrolytic kinetic resolution; MAO inhibitors; phenyl propylene oxide; selegiline;

机译：钴基手性salen配合物;水解动力学拆分;MAO抑制剂;苯环氧丙烷;司来吉兰;

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专利

1. Synthesis of (R)-selegiline via hydrolytic kinetic resolution [J] . Kondekar N.B., Kumar P. Synthetic Communications . 2011,第7a9期

机译：水解动力学拆分合成（R）-司来吉兰
2. Synthesis of key intermediate for (+)-tofacitinib through Co-III(salen)-catalyzed two stereocentered hydrolytic kinetic resolution of (+/-)-methyl-3-(oxiran-2-yl)butanoate [J] . Kamble Rohit B., Suryavanshi Gurunath Synthetic Communications . 2018,第9a12期

机译：通过CO-III（Salen）的（+） - Tofacitinib的关键中间体合成 - 催化（+/-） - 甲基-3-（Oxiran-2-yl）丁酸盐的两种立体沉积水解动力学分辨率
3. Design and synthesis of binuclear Co-salen catalysts for the hydrolytic kinetic resolution of epoxides [J] . Wu Fengshou, Wang Kai, Li Zaoying, Catalysis Communications . 2015,第Null期

机译：用于环氧化物水解动力学拆分的双核Co-salen催化剂的设计与合成
4. HYDROLYTIC KINETIC RESOLUTION (HKR) OF EPOXIDES AS A KEY STEP IN THE SYNTHESIS OFINSECT PHEROMONES [C] . SHARON CHOW 10th international symposium on fine chemistry and functional polymers . 2000

机译：环氧丙烷的水解动力学拆分（HKR）是昆虫信息素合成的关键步骤
5. Rational Design of Polymer-Supported Cobalt (III) Salen Catalysts for the Hydrolytic Kinetic Resolution of Terminal Epoxides. [D] . Kahn, Michael G.C. 2013

机译：聚合物负载钴（III）Salen催化剂的合理设计，用于末端环氧化合物的水解动力学拆分。
6. Mechanistic Basis for High Stereoselectivity and Broad Substrate Scope in the (salen)Co(III)-Catalyzed Hydrolytic Kinetic Resolution [O] . David D. Ford, Lars P. C. Nielsen, Stephan J. Zuend, -1

机译：（salen）Co（III）催化水解动力学拆分中高立体选择性和广泛底物范围的机理基础
7. Concise Enantioselective Syntheses of (+)-L-733,060 and (2S,3S)-3-Hydroxypipecolic Acid by Cobalt(III)(salen)-Catalyzed Two-Stereocenter Hydrolytic Kinetic Resolution of Racemic Azido Epoxides [O] . Arumugam Sudalai, Dattatray Devalankar, Pandurang Chouthaiwale 2013

机译：通过钴（III）（Salen）的（+） - L-733,060和（2S，3S）-3-羟基吡咯酸（Salen）的简洁映选择性合成 - 外消旋氮杂环氧化物的二立体封闭水解动力学分辨率
8. Hydrolytic Kinetic Resolution of Cyclic Substrates. [R] . Jacobsen, E. N., Tikunaga, M., Larrow, J. F. 2005

机译：循环基质的水解动力学拆分。

Synthesis of (R)-selegiline via hydrolytic kinetic resolution

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