RHODIUM-CATALYZED HYDROFORMYLATION OF 2-VINYL- AND 3-VINYL-1-TOSYLPYRROLES AS A CONVENIENT SYNTHETIC ROUTE TO THE CORRESPONDING 2-(1-TOSYLPYRROLYL)PROPANALS AND DERIVATIVES

Settambolo R.; Lazzaroni R.; Caiazzo A.

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RHODIUM-CATALYZED HYDROFORMYLATION OF 2-VINYL- AND 3-VINYL-1-TOSYLPYRROLES AS A CONVENIENT SYNTHETIC ROUTE TO THE CORRESPONDING 2-(1-TOSYLPYRROLYL)PROPANALS AND DERIVATIVES

机译：铑催化的2-乙烯基和3-乙烯基-1-甲苯基的甲酰化羰基反应是相应的2-（1-甲苯基甲苯基）丙烷和衍生物的简便合成路线

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2-(1-Tosylpyrrolyl)propanals 2a-b were conveniently prepared (70% yield) via rhodium-catalyzed hydroformylation of the corresponding 2-vinyl- and 3-vinyl-1-tosylpyrroles 1a-b and successfully transformed into some new derivatives (50-90% yield). [References: 11]

机译：通过相应的2-乙烯基-和3-乙烯基-1-甲苯基吡咯1a-b的铑催化加氢甲酰化反应，可以方便地制备2-（1-甲苯基吡咯基）丙醛2a-b（70％收率），并成功地转化为一些新的衍生物（ 50-90％的产率）。 [参考：11]

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《Synthetic Communications》 |1997年第23期|共10页
作者
Settambolo R.; Lazzaroni R.; Caiazzo A.;
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正文语种 eng
中图分类有机化学;
关键词
Alpha-regioselectivity; Pressure; Styrene;

机译：α-区域选择性;压力;苯乙烯;

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专利

1. RHODIUM-CATALYZED HYDROFORMYLATION OF 2-VINYL- AND 3-VINYL-1-TOSYLPYRROLES AS A CONVENIENT SYNTHETIC ROUTE TO THE CORRESPONDING 2-(1-TOSYLPYRROLYL)PROPANALS AND DERIVATIVES [J] . Settambolo R., Lazzaroni R., Caiazzo A. Synthetic Communications . 1997,第23期

机译：铑催化的2-乙烯基和3-乙烯基-1-甲苯基的甲酰化羰基反应是相应的2-（1-甲苯基甲苯基）丙烷和衍生物的简便合成路线
2. New Synthetic Route to Pharmacologically Active 1-(N-dialkylamino)-3,3-diarylpropanesvia Rhodium-Catalyzed Hydroformylation of 1,1-Diarylethenes [J] . Carlo Botteghi, Lamberto Cazzolato, Mauro Marchetti, The Journal of Organic Chemistry . 1995,第20期

机译：铑催化的1，1-二芳烃的羰基化合成具有药理活性的1-（N-二烷基氨基）-3,3-二芳基丙烷的新合成途径
3. Rhodium-catalyzed one-pot hydroformylation-cyclization of allylbenzene derivatives: Simple and efficient route to 5,6-dihydronaphthalenes [J] . Mouheddin Alhaffar, Rami Suleiman, Bassam El Ali Catalysis Communications . 2010,第8期

机译：铑催化的烯丙基苯衍生物的一锅加氢甲酰化环化：简单高效的5,6-二氢萘途径
4. A convenient synthetic procedure yielding 2-picolinamino-N,Ndiaceticacid monoamide derivatives, for labelling with the fac-M(CO)3+ core [C] . A.E.Chiotellis, Ch.Tsoukalas, M.Pelecanou, Trends in Radiopharmaceuticals(ISTR-2005) . 2007

机译：一种方便的合成方法，可生成2-吡啶甲酸氨基-N，N-醋二乙酸单酰胺衍生物，用于用fac-M（CO）3+核标记
5. Synthetic and Mechanistic Studies of Rhodium-Catalyzed Asymmetric Hydroformylation with Diazaphospholane Ligands [D] . Watkins, Avery L. 2010

机译：铑氮杂二膦烷配体催化铑催化不对称羰基化反应的合成及机理研究
6. RAFT Aqueous Dispersion Polymerization of N-(2-(Methacryloyloxy)ethyl)pyrrolidone: A Convenient Low Viscosity Route to High Molecular Weight Water-Soluble Copolymers [O] . Victoria J. Cunningham, MatthewJ. Derry, Lee A. Fielding, -1

机译：N-（2-（甲基丙烯酰氧基氧基）乙基）吡咯烷酮的RAFT水性分散聚合：通往高分子量水溶性共聚物的便捷低粘度途径
7. Rhodium-Catalyzed Enantioselective Anti-Markovnikov Hydroformylation of Substituted Acryl Acid Derivatives [O] . -1

机译：铑催化的映选择性抗Markovnikov丙烯酸衍生物的加氢甲酰化

RHODIUM-CATALYZED HYDROFORMYLATION OF 2-VINYL- AND 3-VINYL-1-TOSYLPYRROLES AS A CONVENIENT SYNTHETIC ROUTE TO THE CORRESPONDING 2-(1-TOSYLPYRROLYL)PROPANALS AND DERIVATIVES

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