Stereoselective synthesis of (E)-4-cyano-gamma,delta-unsaturated nitriles

Shen YC.; Zhang ZH.

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Stereoselective synthesis of (E)-4-cyano-gamma,delta-unsaturated nitriles

机译：（E）-4-氰基-γ，δ-不饱和腈的立体选择性合成

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(E)-4-Cyano-gamma,delta-unsaturated nitriles were synthesized from the HMPA promoted sequential transformations of diethyl (cyanomethyl)phosphonate potassium tert-butoxide, acrylonitrile and aldehydes in 71-83% yield. [References: 12]

机译：（E）-4-氰基-γ，δ-不饱和腈是由HMPA促进的二乙基（氰甲基）膦酸叔丁醇钾，丙烯腈和醛的顺序转化而合成的，产率为71-83％。 [参考：12]

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《Synthetic Communications》 |2000年第3期|共9页
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Shen YC.; Zhang ZH.;
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正文语种 eng
中图分类有机化学;
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Esters;

机译：酯类;

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1. Stereoselective synthesis of (E)-4-cyano-gamma,delta-unsaturated nitriles [J] . Shen YC., Zhang ZH. Synthetic Communications . 2000,第3期

机译：（E）-4-氰基-γ，δ-不饱和腈的立体选择性合成
2. Stereoselective synthesis of delta-amino-alpha,beta,gamma,delta-unsaturated cycloketones via Mannich-type reaction [J] . Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2020,第17期

机译：甘蓝型反应的δ-氨基-α，β，γ，δ不饱和环氧基酮的立体选择性合成
3. Palladium-Catalyzed Ring-Opening of 2-Alkylidenecyclobutanols: Stereoselective Synthesis of gamma, delta-Unsaturated Ketones by C-C Bond Cleavage [J] . Chen Ling, Sun Feng-Na, Sun Yu-Li, Advanced synthesis & catalysis . 2018,第3期

机译：钯催化的2-烷基苄丁醇的开环：C-C键切割的立体选择合成γ，δ不饱和酮
4. Functionalization of Organogermanium Compounds: Stereoselective Synthesis of Triols and Regioselective Synthesis of Dienes [C] . Yohei Minami, Akihito Konishi, Makoto Yasuda 日本化学会春季年会講演予稿集 . 2018

机译：有机吡喃化合物的官能化：三醇的立体选择性合成及分子区域选择性合成
5. The stereoselective synthesis of nitrile amino acids using a chiral Schiff base complex. [D] . Connolly, Lori C. 2005

机译：使用手性席夫碱配合物立体选择性合成腈氨基酸。
6. Stereoselective Synthesis of Spirooxindole Amides through Nitrile Hydrozirconation [O] . Chunliang Lu, Qing Xiao, Paul E. Floreancig -1

机译：通过锆氢化丁腈酰胺spirooxindole的立体选择性合成
7. Total Synthesis of ()-Mitrephorone A Enabled by Stereoselective Nitrile Oxide Cycloaddition and Tetrasubstituted Olefin Synthesis [O] . -1

机译：通过立体腈氧化物环加成和四氢烯烃合成使得（）-Mitorphorone A的总合成
8. Enolboration 7. Dicyclohexyliodoborane, a Highly Stereoselective Reagent For theEnolboration Of Tertiary Amides. Effects of Solvent And Aldolization Temperature on Stereochemistry Achieving the Stereoselective Synthesis of Either Syn or Anti Aldols [R] . Ganesan, K., Brown, H. C. 1994

机译：配合7.二环己基碘硼烷，一种高立体选择性试剂，用于叔酰胺的合成。溶剂和醛醇化温度对立体化学实现syn或anti aldols立体选择性合成的影响

Stereoselective synthesis of (E)-4-cyano-gamma,delta-unsaturated nitriles

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