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首页> 外文期刊>Synthetic Metals >CRYSTAL STRUCTURE AND POLYMORPHISM OF DIMETHYL-OLIGOTHIOPHENES CRYSTALLIZED EPITAXIALLY ON HIGHLY ORIENTED PTFE THIN FILMS
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CRYSTAL STRUCTURE AND POLYMORPHISM OF DIMETHYL-OLIGOTHIOPHENES CRYSTALLIZED EPITAXIALLY ON HIGHLY ORIENTED PTFE THIN FILMS

机译:高度定向的PTFE薄膜上二甲基-低聚邻苯二酚的晶体结构和多态性

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摘要

The crystal structure of dimethyl-oligothiophenes grown by epitaxial crystallization on highly oriented PTFE thin film has been studied by transmission electron microscopy. The dimethyl-oligothiophenes crystallize principally in a monoclinic phase with common lattice parameters a,b, and beta, but different c for different numbers of thiophene rings: a=0.598nm, b=O.789nm, and beta=98 degrees; and c=1.86nm for tetramer, c=2.234nm for the pentamer and c=2.596nm for the hexamer. The space group is C2/m. Polymorphism is found with coexistence of monoclinic and orthorhombic crystal structures. [References: 4]
机译:通过透射电子显微镜研究了在高取向PTFE薄膜上外延结晶生长的二甲基-低聚噻吩的晶体结构。二甲基-低聚噻吩主要在具有共同晶格参数a,b和β的单斜晶相中结晶,但是对于不同数目的噻吩环,其c不同:a = 0.598nm,b = O.789nm和beta = 98度;对于四聚体,c = 1.86nm,对于五聚体,c = 2.234nm,对于六聚体,c = 2.596nm。空间组为C2 / m。发现多态性与单斜晶体和正交晶体结构共存。 [参考:4]

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