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首页> 外文期刊>Philosophical Magazine Letters >Formation of a 'splitting pattern' associated with L1_2 precipitates in Ir-Nb alloys
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Formation of a 'splitting pattern' associated with L1_2 precipitates in Ir-Nb alloys

机译:Ir-Nb合金中与L1_2析出物有关的“分裂模式”的形成

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A cuboidal L1_2 phase forms in the fcc matrix of an Ir-Nb alloy. Under some conditions, a rod- or plate-like fcc structure can be observed in this phase. This is similar to the splitting pattern' observed in some Ni-based alloys. To understand the formation mechanism of this structure, samples were heated under different conditions. Microstructure evolution during ageing was observed by transmission electron microscopy. We observed a splitting pattern only when the L1_2 precipitates were already formed in the as-cast condition after additional heat treatment at the ageing temperature. In this case, the composition of the L1_2 phase was not equilibrated. We conclude that the splitting pattern appears owing to a kinetic phenomenon when the L1_2 phase changes to the equilibrium composition.
机译:在Ir-Nb合金的fcc基质中形成长方体的L1_2相。在某些条件下,在此阶段可以观察到棒状或板状fcc结构。这类似于在某些镍基合金中观察到的分裂模式。为了了解这种结构的形成机理,在不同条件下加热样品。通过透射电子显微镜观察了老化过程中的微观结构演变。我们仅在经过时效温度下的额外热处理后,在铸态条件下已经形成L1_2沉淀物时才观察到裂痕。在这种情况下,L1_2相的组成不平衡。我们得出的结论是,当L1_2相变为平衡组成时,由于动力学现象而出现了分裂模式。

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