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首页> 外文期刊>Physica Scripta: An International Journal for Experimental and Theoretical Physics >Excitation energies, oscillator strengths and radiative rates in triply ionised phosphorous
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Excitation energies, oscillator strengths and radiative rates in triply ionised phosphorous

机译:三重电离磷的激发能,振荡器强度和辐射率

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We have calculated the excitation energies for the lowest 23 LS and 43 fine-structure levels as well as oscillator strengths and radiative decay rates for the transitions among (1s(2)2s(2)2p(6))3s(2) (S-!), 3s3p ((1,3)p(0)) 3p(2) (S-1, P-3, D-1), 3s3d (D-1,D-3), 3s4s (S-1,S-3) 3p3d (P-1,3(0), D-1,3(0), F-1,3(0)), 3s4p (P-1,P-3), 3s4d (D-1,D-3), 3s4f (F-1,3(0)) and 3p4s (P-1,3(0)) states in P IV These states are represented by extensive configuration-interaction (CI) wavefunctions obtained with the CIV3 computer code of Hibbert. The calculations have been carried out in both LS and intermediate-coupling schemes. Relativistic effects are included through the Breit-Pauli approximation via spin-orbit, spin-other-orbit, spin-spin, Darwin and mass correction terms: We have also calculated the radiative lifetimes from our radiative decay rates. Our results are compared with other theoretical calculations and the available experimental data. [References: 39]
机译:我们已经计算出最低的23 LS和43精细结构能级的激发能以及(1s(2)2s(2)2p(6))3s(2)之间的跃迁的振荡器强度和辐射衰减率(S -!),3s3p((1,3)p(0))3p(2)(S-1,P-3,D-1),3s3d(D-1,D-3),3s4s(S-1 ,S-3)3p3d(P-1,3(0),D-1,3(0),F-1,3(0)),3s4p(P-1,P-3),3s4d(D- P IV中的1,D-3),3s4f(F-1,3(0))和3p4s(P-1,3(0))状态这些状态由使用希伯特的CIV3计算机代码。 LS和中间耦合方案均已进行了计算。相对论效应通过自旋轨道,自旋其他轨道,自旋自旋,达尔文和质量校正项通过Breit-Pauli近似包括在内:我们还根据辐射衰减率计算了辐射寿命。我们的结果与其他理论计算和可用的实验数据进行了比较。 [参考:39]

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