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Globally accurate theory of structure and thermodynamics for soft-matter liquids

机译:全球性的软物质液体结构和热力学理论

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Standard statistical mechanical approximations (e.g. mean-field approximations) for pair-correlation functions of strongly interacting systems that yield adequate thermodynamics away from critical points typically break down badly in critical regions. The self-consistent Ornstein-Zemike approximation (SCOZA) transcends this difficulty, yielding globally accurate Structure and thermodynamics. The SCOZA has been applied successfully to a variety of Hamiltonian models and the result will be briefly summarized. We end with a progress report on the applications of the SCOZA to some soft-matter systems. (C) 2002 Published by Elsevier Science B.V. [References: 37]
机译:用于强相互作用系统的成对相关函数的标准统计机械近似值(例如平均场近似值)通常会在关键区域严重分解,从而产生足够的热力学值而远离关键点。自洽的Ornstein-Zemike逼近(SCOZA)克服了这一难题,产生了全球准确的结构和热力学。 SCOZA已成功应用于各种哈密顿量模型,并将简要总结其结果。我们以关于SCOZA在某些软物质系统上的应用的进度报告结尾。 (C)2002由Elsevier Science B.V.出版[参考:37]

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