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首页> 外文期刊>Physica, B. Condensed Matter >Electromagnetic properties of superparamagnetic nanocomposites
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Electromagnetic properties of superparamagnetic nanocomposites

机译:超顺磁性纳米复合材料的电磁性能

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We report here new experimental results on superparamagnetic nanocomposites. We compare experimental transmission measurements with calculations based on the Onsager local field, taking into account the permanent magnetic moment of the particles. Optical measurements are performed on a Fourier transform spectrometer in the far infrared range, and on a microwave setup. Usually, superparamagnetic relaxation is understood by comparing the relaxation time tau of the magnetic moment of the particle with the measuring time tau(m). According to Ni el's model tau is temperature dependent. In our case, tau(m) is given by the electromagnetic wave period. As this experimental technique has been proved to be relevant to investigate superparamagnetism relaxation, we check it with two kinds of nanocomposites: Ni (ferromagnetic) embedded in alumina or aluminum nitride matrix and gamma-Fe2O3 particles (ferrimagnetic) in a polymer. The dominant anisotropy is magnetocrystalline for Ni and shape and/or surface for gamma-Fe2O3. This difference leads to different transmission behaviors while changing sample temperature from 5 to 300 K. The magnetocrystalline anisotropy shows up temperature dependence while the shape or surface anisotropies do not. (C) 2000 Elsevier Science B.V. All rights reserved. [References: 7]
机译:我们在这里报告有关超顺磁性纳米复合材料的新实验结果。我们将实验的透射测量结果与基于Onsager局部场的计算进行了比较,并考虑了颗粒的永久磁矩。光学测量是在傅立叶变换光谱仪上在远红外范围内以及在微波装置上进行的。通常,通过将粒子磁矩的弛豫时间tau与测量时间tau(m)进行比较,可以理解超顺磁弛豫。根据Ni el模型,tau与温度有关。在我们的情况下,tau(m)由电磁波周期给出。由于已证明该实验技术与研究超顺磁性弛豫有关,因此我们使用两种纳米复合材料对其进行了检查:嵌入氧化铝或氮化铝基体中的Ni(铁磁性)和聚合物中的γ-Fe2O3颗粒(亚铁磁性)。镍的主要各向异性是磁晶的,而γ-Fe2O3的形状和/或表面是主要的。在将样品温度从5 K更改为300 K时,这种差异导致不同的传输行为。磁晶各向异性表现出温度依赖性,而形状或表面各向异性则没有。 (C)2000 Elsevier Science B.V.保留所有权利。 [参考:7]

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