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Thermal and Electron-Induced Behavior of d (sub 6)-Benzene-Chromium-TricarbonylAdsorbed on Ag(111)

机译:吸附在ag(111)上的d(sub 6) - 苯 - 铬 - 三羰基的热和电子诱导行为

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Deuterated benzene-chromium-tricarbonyl (C6D6Cr(CO)3) adsorbed on Ag(111) hasbeen studied with electron-stimulated desorption, temperature-programmed desorption and Auger electron spectroscopy. C6D6Cr(CO)3 adsorbs non-dissociatively at 90 K on this surface, reversibly desorbing near 300 K (monolayer) and 275 K (multilayers) without thermal decomposition. Low-energy (220 eV) electron bombardment of monolayer C6D6Cr(CO)3 induces the decomposition of the parent molecules by breaking Cr-CO or Cr-C6D6 bonds, and the production of surface-bound benzene-CO-Cr complexes. The total decomposition cross section for

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