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Attenuated Total Reflection Fourier-Transform Infrared Spectroscopic Study of Ion-Solvent and Ion-Ion Interactions in Alkali-Metal Perchlorate-Acetonitrile. (Reannouncement with New Availability Information)

机译：碱金属高氯酸盐 - 乙腈中离子溶剂和离子 - 离子相互作用的衰减全反射傅立叶变换红外光谱研究。（重新公布新的可用性信息）

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A detailed study of the effect of alkali-metal perchlorates, especially LiClO4and NaClO4, on the spectral features of acetonitrile has been made using attenuated total reflection FTIR spectroscopy. The effect of the electrolyte on the C-H stretching and deformation modes together with new information on the C equivalent N and C-C stretching modes is analysed in detail. It is shown on the basis of spectra obtained in the deuteriated acetonitrile that the Cl-O symmetrical stretching vibration (Vl) is IR active when the anion is paired to a cation. Analysis of the perchlorate region of the spectrum provided further information on ion pairing in this system.

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Fawcett, W. R.; Liu, G.; Faguy, P. W.; Foss, C. A.; Motheo, A. J.;
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年度 1993
页码
总页数 8
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Acetonitrile; Alkali metals; Perchlorates; Vibrational spectra; Fourierspectroscopy; Infrared spectroscopy; Anions; Cations; Deformation; Electrolytes; Ions; Metals; Reflection; Spectra; Spectroscopy; Reprints;

机译：乙腈;碱金属;高氯酸盐;振动光谱;傅里叶光谱;红外光谱;阴离子;阳离子;变形;电解质;离子;金属;反射;光谱;光谱学;重印;

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机译：高氯酸锂 - 硝基甲烷溶液中离子溶剂和离子 - 离子相互作用的衰减全反射傅里叶变换红外光谱研究

Attenuated Total Reflection Fourier-Transform Infrared Spectroscopic Study of Ion-Solvent and Ion-Ion Interactions in Alkali-Metal Perchlorate-Acetonitrile. (Reannouncement with New Availability Information)

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