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Reaction of 1,4-poly(2-trimethylsilylmetyl-1,3-butadiene) with Phenylsulfenyl Chloride. Synthesis of Poly(3-methylene-2-phenylthiobutane)

机译：1,4-聚（2-三甲基甲硅烷基甲基-1,3-丁二烯）与苯基亚磺酰氯的反应。聚（3-亚甲基-2-苯硫基丁烷）的合成

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There is considerable interest in chemical modification of intact polymers (1 3). Electrophilic substitution with allylic rearrangement and loss of the silyl group is a characteristic reaction of monomeric allylic silanes. Similar reaction have not been explored with polymeric systems. Reaction of 1,4-poly(2-trimethylsilylmethyl-1-1,3-butadiene) with phenylsulfenyl chloride yields predominantly poly(3- methylene-2-phenyl-thiobutane). The mechanism of this reaction is discussed. The product polymer has been characterized by 1H 13C NMR, IR, GPC, TGA, and elemental analysis. Butadienes, Reprints, Butanes, Phenylradicals. (MJM)

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Ding, Y. X.; Weber, W. P.;
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年度 1988
页码 p.1-5
总页数 5
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Butanes; Polymers; Butadienes; Chemical properties; Chlorides; Modification; Reprints; Substitutes; Yield; Organic sulfur compounds; Methyl radicals; Silanes; Phenyl radicals;

机译：丁烷;聚合物;丁二烯;化学性质;氯化物;改性;重印;替代品;产率;有机硫化合物;甲基;硅烷;苯基;

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Reaction of 1,4-poly(2-trimethylsilylmetyl-1,3-butadiene) with Phenylsulfenyl Chloride. Synthesis of Poly(3-methylene-2-phenylthiobutane)

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