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Organoarsenic Compounds II. Separation and Stereochemical Determination of 5-Substituted 2-Phenyl-1,3,2-Dithiarsenanes

机译：有机砷化合物II。 5-取代2-苯基-1,3,2-二硫杂环庚烷的分离和立体化学测定

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The cis- and trans-isomers of 5-substituted 2-phenyl-1,3,2- dithiarsenanes (compounds 5 and 6) are the adducts of the lewisite simulant, phenyl dichloroarsine (3), and the 2-substituted 1,3-propanedithiols (1 and 2). The isomers were separated by reverse-phase liquid chromatography and identified by photodiode-array/mass spectrometry. The stereochemistry of these adducts is assigned based on H1 NMR Nuclear Overhauser Effect difference measurements.

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Bossie, P. C. ; Hsu, F. ; Wagner, G. W. ; Rohrbaugh, D. K.;
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年度 2001
页码 1-23
总页数 23
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Spectra; Stereochemistry; Liquid chromatography; Lewisite;

机译：光谱;立体化学;液相色谱; Lewisite;

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2. Stereochemical Resolution of Racemates, in HPLC, Using a Chiral Stationary Phase Based Upon Immobilized #alpha#-Chymotrypsin. II. Enzyme Chiral Separations [J] . G. Felix, V. Descorps Chromatographia . 1999,第11a12期

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机译：HPLC-ICP-MS测定精加工鸡饲料和鸡凋落物中有机静脉化合物
5. I. Protein design: Reengineering cellular retinoic acid binding protein II into a retinal binding protein. II. Pseudo-caged compounds as chromophoric hosts for the absolute stereochemical determination of chiral compounds. [D] . Vasileiou, Chrysoula. 2005

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7. The Chemical Behavior of Low Valence Sulfur Compounds. II. Thin-layer Chromatographic Separation and Photometric Determination of Low Valence Sulfur Compounds [O] . Kunishige Naito, Shinsuke Takei, Taijiro Okabe 1970

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Organoarsenic Compounds II. Separation and Stereochemical Determination of 5-Substituted 2-Phenyl-1,3,2-Dithiarsenanes

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