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Dependence of Capacitance of Metal-Molten Salt Interface on Local Density Profiles Near Electrode

机译：金属熔盐界面电容对近电极局部密度分布的依赖性

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摘要

The mean spherical approximation applied to a metal-molten salt interface is generalized to take further account of the local density profiles near the electrode. The temperature dependence of the differential capacitance is shown to arise, in large measure from such local structure. However, the hard wall assumption for the electrode is retained and this must be kept in mind in comparing our model results with experiment. (Atomindex citation 15:069723)

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作者
Ballone, P.; Pastore, G.; Tosi, M. P.; Painter, K. R.; Grout, P. J.;
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年度 1983
页码 1-17
总页数 17
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Molten Salts; Capacitance; Electrodes; Interfaces; Ion Density; Metals; Temperature Dependence;

机译：熔盐;电容;电极;界面;离子密度;金属;温度依赖性;

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2. Joint density functional theory of the electrode-electrolyte interface: Application to fixed electrode potentials, interfacial capacitances, and potentials of zero charge [J] . Kendra Letchworth-Weaver, T. A. Arias Physical review . 2012,第7期

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3. Thickness and Density Profiles of Polyelectrolyte Brushes: Dependence on Grafting Density and Salt Concentration [J] . G. Romet-Lemonne, J. Daillant, P. Guenoun, Physical review letters . 2004,第14期

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4. LOCAL ELECTRON DENSITY PROFILE NEAR THE SAMPLE BOUNDARY INVESTIGATED BY MAGNETO-CAPACITANCE IN QUANTUM HALL REGIME [C] . K. OTO, M. KIMURA, Y. MIWA International Conference on High Magnetic Fields in Semiconductor Physics . 2005

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5. AC IMPEDANCE AND DIFFERENTIAL PHOTOCURRENT TECHNIQUES FOR MONITORING SURFACE STATE PROPERTIES AT THE SEMICONDUCTOR/ELECTROLYTE INTERFACE (PHOTOELECTROCHEMISTRY, CELL, ELECTRODE, CAPACITANCE, CONDUCTANCE) [D] . WHEELER, BOB LEE 1985

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6. Crowding and Anomalous Capacitance at an Electrode–IonicLiquid Interface Observed Using Operando X-ray Scattering [O] . Miaoqi Chu, Mitchell Miller, Pulak Dutta, 2016

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7. Joint Density-Functional Theory of the Electrode-Electrolyte Interface: Application to Fixed Electrode Potentials, Interfacial Capacitances, and Potentials of Zero Charge [O] . Kendra Letchworth-weaver, T. A. Arias 2014

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8. Effect of Microscopic Structure of Metal Electrode on Capacitance of Metal - Molten Salt Interface [R] . Roman, E., Tosi, M. P., Grout, P. J., 1985

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Dependence of Capacitance of Metal-Molten Salt Interface on Local Density Profiles Near Electrode

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