首页> 外国专利> MODIFIED PLANAR CELL AND STACK OF ELECTROCHEMICAL DEVICES BASED THEREON, METHOD FOR PRODUCING THE PLANAR CELL AND THE STACK, AND MOULD FOR PRODUCING THE PLANAR CELL

MODIFIED PLANAR CELL AND STACK OF ELECTROCHEMICAL DEVICES BASED THEREON, METHOD FOR PRODUCING THE PLANAR CELL AND THE STACK, AND MOULD FOR PRODUCING THE PLANAR CELL

机译:基于其的电化学设备的改性平面细胞和堆叠,制备平面细胞和堆叠的方法以及制备平面细胞的模具

摘要

The invention relates to a modified planar cell with a solid-oxide solid electrolyte, a gas-diffuse anode, a cathode, a metal or oxide current path and a current-gas supply. The supporting solid electrolyte of the cell is in the form of a corrugated plate consisting of corrugations. In cross-section, the corrugations of the plate constitute an isosceles, identical-height trapezium, without a larger lower base with holes. The holes are formed on one side in the upper part of each corrugation, for supplying one of the reagents, e.g. fuel in case of a fuel cell. The corrugations are connected to one another at their base in order to form gas space channels of the cell. The gas space channels are in the form of inverted isosceles trapezia without a larger upper base and the angle alpha at their smaller base is 0.1 to 89.9°. The corrugated plate is connected to two opposing walls, a front wall and a rear wall. The latter is arranged perpendicular to the corrugations of the plate and thus of equal height, and is furnished with holes. The holes in one wall are used for introducing a second reagent, e.g. air in the case of a fuel cell, into each channel of the electrode environment in the form of inverted isosceles trapezia without the larger upper base and the holes of the other opposing wall for discharging the hypoxic mixture. On one side of the gas space channels constituting, in cross-section, an isosceles trapezium without larger lower base, the corrugated plate of the supporting solid electrode is coated with an electrode, e.g. a nickel-cermet anode in the case of a fuel cell. On the side of the gas space channels of the electrode environment, which are shaped in the form of inverted isosceles trapezia without the larger upper base, the plate is coated with a second, counter-electrode, e.g. a cathode based on strontium-lanthanum-manganite. The metallic box-like gas supply duct ensures the supply of reagents and the discharge of reaction products with a series of holes. The width and the length of the gas supply duct coincide with those of the cell. These holes correspond to the holes in the upper parts of the corrugations of the cell that constitute, in cross-section, an isosceles trapezium without a larger lower base and are connected in a gas-tight manner to the periphery of the holes. A gas-tight space is formed in the planar cell for the reagent introduced via a tube, for the uniform distribution thereof via the gas space channels and for the exit of the exhaust gases through a similar discharge gas manifold. The discharge gas manifold is rotated by 180° relative to the vertical axis and is connected in a gas-tight manner to the ceramic part at the periphery. The flat surfaces of the gas manifolds furnished with holes are connected to the electrodes. They are simultaneously used as current collectors and the tubes are used as current terminals of the planar cell.
机译:本发明涉及一种改进的平面电池,其具有固体氧化物固体电解质,气体扩散阳极,阴极,金属或氧化物电流路径以及电流气体供应。电池的支撑固体电解质为由波纹构成的波纹板的形式。在横截面中,板的波纹构成等腰,等高梯形,而没有较大的下部带孔底部。在每个波纹的上部的一侧上形成孔,用于供应例如一种或多种试剂。如果是燃料电池,则为燃料。波纹在其底部彼此连接,以形成电池的气体空间通道。气体空间通道呈倒等腰梯形,没有较大的上底,在其较小底上的夹角α为0.1至89.9°。波纹板连接到两个相对的壁,即前壁和后壁。后者垂直于板的波纹布置并因此具有相等的高度,并设有孔。一个壁上的孔用于引入第二种试剂,例如第二种试剂。在燃料电池的情况下,空气以倒等腰梯形的形式进入电极环境的每个通道,而没有较大的上基座和另一个相对壁的孔,以排出低氧混合物。在构成等腰梯形而没有较大下底的横截面的气体空间通道的一侧上,支撑固体电极的波纹板涂覆有例如碳纳米管的电极。在燃料电池中为镍金属陶瓷阳极。在电极环境的气体空间通道的一侧,该通道以倒等腰梯形的形式形成,而没有较大的上基座,该板涂覆有第二反电极,例如第二电极。基于锶-镧-锰的阴极。金属的盒状气体供应管道可确保试剂的供应和带有一系列孔的反应产物的排放。气体供应管道的宽度和长度与电池的宽度和长度一致。这些孔对应于电池的波纹的上部中的孔,该孔的横截面构成等腰梯形而没有较大的下底并且以气密方式连接到孔的外围。在平面单元中形成气密空间,用于通过管引入的试剂,通过气体空间通道的均匀分布以及用于通过相似的排气歧管排出的废气。排气歧管相对于竖直轴线旋转180°,并且以气密方式连接至周边的陶瓷部件。带有孔的气体歧管的平坦表面连接到电极。它们同时用作集电器,而管用作平面单元的电流端子。

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