首页> 外国专利> 2,5-BIS-(4-AMINOPHENYLTHIO)-1,3,4-THIADIASOL OR 2,5-BIS)4-AMINOPHENYL-SULFONYL)-1,3,4-THIADIASOL AS LIGHT STABILIZERS OF CELLULOSE ACETATE

2,5-BIS-(4-AMINOPHENYLTHIO)-1,3,4-THIADIASOL OR 2,5-BIS)4-AMINOPHENYL-SULFONYL)-1,3,4-THIADIASOL AS LIGHT STABILIZERS OF CELLULOSE ACETATE

机译:2,5-BIS-(4-氨基苯甲硫基)-1,3,4-噻二酚或2,5-BIS)4-氨基苯甲磺酰基)-1,3,4-噻二唑作为醋酸纤维素的光稳定剂

摘要

The invention relates to heterocyclic compounds, in particular to 2,5bis (4-aminophenylthio) -1,3,4-thiadiazole or 2,5bis (4-aminophenylsulfonyl) -1,3,4-thia diazole which may find use as light stabilizers of cellulose acetate. The goal - the creation of new compounds, are more active. Preparation lead condensation of equimolar amounts of 2,5-dimercapto-1,3,4-thiadiazole-4-halo- nitrobenzene in a medium of an amide solvent, followed by reducing the obtained dinitro compounds. Yield,% m.p., & amp; deg; C.. Gross-p-la: a) 85; & Amp; deg; 25-227; Ci4HtzN4S3. b) 85; 191-193; SschNiM ZzO. The novel compounds are more effective than the prior art 2, 6-digidroksifeniltio - 1,3,4-thiadiazole. Table 1.
机译:本发明涉及杂环化合物,尤其涉及2,5-双(4-氨基苯硫基)-1,3,4-噻二唑或2,5-双(4-氨基苯基磺酰基)-1,3,4-噻二唑醋酸纤维素的稳定剂。目标-创建新化合物更加积极。在酰胺溶剂的介质中制备等摩尔量的2,5-二巯基-1,3,4-噻二唑-4-卤代硝基苯的铅缩合反应,然后还原得到的二硝基化合物。产率,%mp。&度Gross-p-la:a)85; &Amp;度25-227; Ci4HtzN4S3。 b)85; 191-193; SschNiM ZzO。所述新型化合物比现有技术2、6-二叉基西非尼-1,3,4-噻二唑更有效。表格1。

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