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FORMATION OF NICKEL SILICIDES ONTO (100) SILICON WAFER SURFACES USING A THIN PLATINUM INTERLAYER

机译:使用薄铂金夹层在(100)硅晶片表面上形成镍硅化物

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In this work, Ni(Pt) silicides were obtained starting from Ni/Pt films deposited on (100) silicon substrate and subsequent annealing step at temperatures from 350 to 600℃ for 120 seconds in a Rapid Thermal Processing (RTP) furnace. The deposition process of a Ni(30 nm)/Pt(1.5 nm) bilayer onto Si (100) was e-beam evaporation. The Ni(Pt) silicide films were characterized by Rutherford Backscattering (RBS) spectrometry, X-Ray Diffraction (XRD) analysis. Atomic Force Microscopy (AFM) and four-probe measurements. From these characterization techniques, it was obtained crystallographic phases (XRD), surface micro-roughness (AFM) and, Ni(Pt) silicide stoichiometry and thickness by using RUMP simulations of the RBS spectra. The nickel silicide stoichiometry resulted NiSi for RTP performed at temperatures higher than 400℃ during 120 s. Also, this processing condition led to NiSi surface with low values of Root Mean Square (RMS) micro-roughness (<1.4 nm). Platinum was observed to be distributed along the NiSi film. On the other hand, XRD analysis revealed NiSi phases even for temperatures higher than 400℃ and the silicide resistivity is the lowest at 500℃ and progressively degrades for higher temperatures.
机译:在这项工作中,从沉积在(100)硅基板上的Ni / Pt膜开始,然后在快速热处理(RTP)炉中在350至600℃的温度下退火120秒,获得了Ni(Pt)硅化物。 Ni(30 nm)/ Pt(1.5 nm)双层在Si(100)上的沉积过程是电子束蒸发。通过Rutherford背散射(RBS)光谱,X射线衍射(XRD)分析对Ni(Pt)硅化物膜进行了表征。原子力显微镜(AFM)和四探针测量。通过这些表征技术,通过使用RBS光谱的RUMP模拟,获得了结晶相(XRD),表面微粗糙度(AFM)和Ni(Pt)硅化物化学计量和厚度。硅化镍化学计量法可在120 s内在高于400℃的温度下对RTP使用NiSi。同样,该处理条件导致NiSi表面的均方根(RMS)微粗糙度值较低(<1.4 nm)。观察到铂沿NiSi膜分布。另一方面,XRD分析表明,即使温度高于400℃,NiSi相也是如此;而硅化物的电阻率在500℃时最低,而在更高的温度下,硅化物的电阻率逐渐降低。

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