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Total evaluation of W-Ti absorber for x-ray mask

机译:X射线掩模用W-Ti吸收剂的总评价

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Abstract: W-Ti film was comprehensively investigated for its application as an x-ray mask absorber. A stress-free and amorphous W-Ti film was successfully deposited by dc sputtering with a W-Ti (1 wt%) target using a gas mixture of Ar and N$-2$/. To obtain much lower stress, we firstly improve the accuracy of stress measurement up to $POM 1 MPa, and ultra-low stress film was obtained by step- annealing. The stress of the film has been found stable enough to apply to x-ray masks in an air atmosphere and for x-ray exposure. The density, composition, and microstructure of the film were also evaluated by SEM, XD, XPS, and TDS. The film surface was very smooth and the roughness measured by AFM was about 2 nm. The etching properties of the absorber using a Cr mask, ITO stopper and electron cyclotron resonance (ECR) discharge plasmas were also investigated in order to achieve a resolution of below 0.1 $mu@m. Highly selective and anisotropic etching has been realized using a mixture of SF$-6$/ and CHF$-3$/, by cooling the stage to about $MIN@50$DGR@C under controlled plasma conditions. Moreover, the microfabrication of a smooth W-Ti absorber has been demonstrated for lines and spaces patterns of 0.06 $mu@m and for 1-Gbit-class dynamic random access memory patterns. !16
机译:摘要:对W-Ti薄膜作为X射线掩模吸收剂的应用进行了广泛的研究。使用Ar和N $ -2 $ /的气体混合物通过W-Ti(1 wt%)靶材通过直流溅射成功沉积了无应力的非晶W-Ti膜。为了获得更低的应力,我们首先将应力测量的精度提高到$ POM 1 MPa,然后通过逐步退火获得超低应力膜。已经发现,膜的应力足够稳定,可以在空气气氛中施加到X射线掩模上,并且可以X射线曝光。还通过SEM,XD,XPS和TDS评估膜的密度,组成和微结构。膜表面非常光滑,并且通过AFM测量的粗糙度为约2nm。为了达到低于0.1μm的分辨率,还研究了使用Cr掩模,ITO塞和电子回旋共振(ECR)放电等离子体的吸收体的蚀刻性能。使用SF $ -6 $ /和CHF $ -3 $ /的混合物,通过在受控的等离子体条件下将平台冷却至约$ MIN @ 50 $ DGR @ C,已经实现了高度选择性和各向异性的蚀刻。此外,已经证明了光滑的W-Ti吸收体的微细加工用于0.06μm的线和空间图案以及1-Gbit类的动态随机存取存储器图案。 !16

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