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Investigation into the thermoelectric properties of GaSb/lnAs superlattice structures

机译:GaSb / InAs超晶格结构的热电性能研究

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We report on our investigation into the use of I1I-V superlattice structures for thermoelectric (TE) applications. Preliminary review of I1I-V materials trends indicate that the GaSb/lnAs superlattice system should offer one of the best potentials for high thermoelectric performance in the 500K-800K range. MOCVD growth of GaSb/lnAs superlattice structures was carried out, and relevant structural, thermal, and electrical characterization has been performed. TEM and XRD results demonstrate a well-ordered superlattice structure. Thermal conductivity measurements reveal a reduction in the room-temperature thermal conductivity of GaSb/lnAs superlattices (4.4-10.0 W/m-K), relative to either binary GaSb (32 W/m-K) or InAs (27 W/m-K). Additionally, we have worked to optimize the thermoelectric power factor (aV), studying both Se- and Te-doping of the superlattice structures, in an effort to demonstrate optimal thermoelectric performance. Our results demonstrate a maximum ZT of 0.36 at 400K for optimally doped n-type GaSb/lnAs superlattice structures.
机译:我们报告我们对I1I-V超晶格结构在热电(TE)应用中的使用情况的调查。对I1I-V材料趋势的初步审查表明,GaSb / lnAs超晶格系统应提供500K-800K范围内高热电性能的最佳潜力之一。进行了GaSb / lnAs超晶格结构的MOCVD生长,并进行了相关的结构,热学和电学表征。 TEM和XRD结果表明,有序的超晶格结构。热导率测量表明,相对于二元GaSb(32 W / m-K)或InAs(27 W / m-K),GaSb / InAs超晶格的室温热导率降低(4.4-10.0 W / m-K)。此外,我们还研究了超晶格结构的Se和Te掺杂,以优化热电功率因数(aV),以证明最佳的热电性能。我们的结果表明,最佳掺杂的n型GaSb / lnAs超晶格结构在400K时的最大ZT为0.36。

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