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Adhesion Promotion Study on 0.13 um SiO:C:H Low k /Copper Damascene Process

机译:0.13 um SiO:C:H低k /铜镶嵌工艺的附着力研究

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Low k material delamination during Cu-CMP is one of the major obstructions for low k /Cu integration. Six pre-ARC treatments on SiO:C:H low k dielectric which were low temperature N2O plasma treatment 1 minutes, 2 minutes and high temperature N2O plasma treatment 10 seconds,30 seconds and 1 minute were tried to solve the Cu-CMP peeling. Only the one with low temperature N2O treatment can solve the Cu-CMP edge delamination problem by reducing the surface carbon content via breaking the Si-CH3 and Si-C bonding. The reason why the high temperature N2O treatment dose not work as the low temperature one is that the Si-CH3 bonding was severely damaged and changed to Si-COOH bonding . The acidified surface was not good for the adhesion of the following ARC material.
机译:Cu-CMP过程中的低k材料分层是低k / Cu集成的主要障碍之一。为解决Cu-CMP剥离问题,尝试了在SiO:C:H低k电介质上进行六次ARC前处理:低温N2O等离子体处理1分钟,2分钟和高温N2O等离子体处理10秒,30秒和1分钟。只有经过低温N2O处理的材料才能通过破坏Si-CH3和Si-C键来减少表面碳含量,从而解决Cu-CMP边缘脱层的问题。高温N 2 O处理不能像低温N 2 O处理那样起作用的原因是Si-CH 3键被严重破坏并变为Si-COOH键。酸化的表面不利于以下ARC材料的粘附。

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