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Entropy Production Analysis in Extractive Distillation Using Non-Equilibrium Thermodynamics and a Rate Based Model

机译:采用非平衡热力学和基于速率的熵蒸馏的熵生产分析

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Entropy generation (EG) in an extractive distillation column for ethanol dehydration was determined. The rate based model and non-equilibrium thermodynamics (NET) leads to quantify separately the EG due to interface heat and mass transfer and mixing. Additionally, this model allows estimating the effects of operational conditions such as reflux ratio and feed condition on the EG. The results obtained show that mixing effects at the feeding points (hydrated ethanol and separation agent) and interface mass transfer are the main sources of EG with 55% and 41% of total EG, respectively. The significance of this work is the use of a rate based model and NET theory as a tool for energy use analysis in multicomponent distillation processes. EG analysis is the starting point to define new operational strategies and design characteristics that allow a more efficient energy use.
机译:测定乙醇脱水的熵产生(例如)在乙醇脱水中的熵产生。基于速率的模型和非平衡热力学(网)导致单独量化例如由于界面热量和传质和混合而定量。另外,该模型允许估计例如回流比和馈电条件的操作条件的影响。得到的结果表明,喂食点(水合乙醇和分离剂)和界面传质的混合效果是例如分别为55%和41%的主要来源。这项工作的重要性是使用基于速率的模型和净理论作为多组分蒸馏过程中的能量使用分析的工具。例如,分析是定义新的操作策略和设计特征的起点,允许更有效的能量使用。

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