A New Fully Automated Online SPE/HPLC-MS/MS Method for the Determination of Phenoxycarboxylic Acids in Water

机译：一种新的全自动在线SPE / HPLC-MS / MS / MS方法，用于测定水中苯氧基羧酸的方法

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Phenoxycarboxylic acids like 2,4-D and 2,4,5-T are widely used herbicides and represent a group of chlorinated compounds which are of high interest for the safety of ground water as well as surface water (chemical structures see Figure 1). The most common approach is to perform direct large volume injection of the sample, but LOD's are limited due to the relatively poor response of the compounds in negative electrospray modus. Moreover the matrix effects the ionization process given rise to ion suppression or ion enhancement for the different analytes, potentially leading to incorrect results. In this work a new fully automated method is presented combining cleanup on a low pressure SPE system and a high pressure online SPE system.

机译：苯氧基羧酸如2,4-D和2,4,5-T被广泛使用除草剂，代表一组氯化化合物，对地面水的安全性以及地表水（化学结构见图1）。最常见的方法是进行直接大量的样品注射样品，但由于负电喷雾模式中的化合物的响应相对较差，因此LOD受到限制。此外，基质效应离子化过程给出了不同分析物的离子抑制或离子增强，可能导致不正确的结果。在这项工作中，在低压SPE系统和高压在线SPE系统上将清理结合清理，并提出了一种新的全自动方法。

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《ASMS Conference on Mass Spectrometry and Allied Topics》|2014年||共1页
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Franziska Chmelka; Oscar Cabrices; Edward Pfannkoch;
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中图分类 TB994.5-53;
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1. Development and validation of a fully automated online-SPE-ESI-LC-MS/MS multi-residue method for the determination of different classes of pesticides in drinking, ground and surface water [J] . Mann Oliver, Pock Elisabeth, Wruss Klaus, International journal of environmental analytical chemistry . 2016,第1a5期

机译：全自动在线SPE-ESI-LC-MS / MS多残留方法的开发和验证，该方法用于测定饮用水，地下水和地表水中的各种农药
2. Fully automated trace level determination of parent and alkylated PAHs in environmental waters by online SPE-LC-APPI-MS/MS [J] . Cesar E. Ramirez, Chengtao Wang, Piero R. Gardinali Analytical and bioanalytical chemistry . 2014,第1期

机译：通过在线SPE-LC-APPI-MS / MS全自动测定环境水中母体和烷基化多环芳烃的痕量水平
3. Online solid phase extraction liquid chromatography tandem mass spectrometry (SPE-LC-MS/MS) method for the determination of sucralose in reclaimed and drinking waters and its photo degradation in natural waters from South Florida [J] . Sudha Rani Batchu, Natalia Quinete, Venkata R Panditi, Chemistry central journal . 2013,第1期

机译：在线固相萃取液相色谱串联质谱法（SPE-LC-MS / MS）测定南佛罗里达州再生水和饮用水中的三氯蔗糖及其光降解
4. A New Fully Automated Online SPE/HPLC-MS/MS Method for the Determination of Phenoxycarboxylic Acids in Water [C] . Franziska Chmelka, Oscar Cabrices, Edward Pfannkoch ASMS Conference on Mass Spectrometry and Allied Topics . 2014

机译：一种新的全自动在线SPE / HPLC-MS / MS / MS方法，用于测定水中苯氧基羧酸的方法
5. Development of quantitative bioanalytical methods for the measurement of pharmaceutical compounds via HPLC-UV and HPLC-MS/MS. [D] . McCulloch, Melissa A. 2009

机译：开发用于通过HPLC-UV和HPLC-MS / MS测定药物化合物的定量生物分析方法。
6. Online solid phase extraction liquid chromatography tandem mass spectrometry (SPE-LC-MS/MS) method for the determination of sucralose in reclaimed and drinking waters and its photo degradation in natural waters from South Florida [O] . Sudha Rani Batchu, Natalia Quinete, Venkata R Panditi, 2013

机译：在线固相萃取液相色谱串联质谱法（SPE-LC-MS / MS）测定南佛罗里达州再生水和饮用水中的三氯蔗糖及其光降解
7. Online solid phase extraction liquid chromatography tandem mass spectrometry (SPE-LC-MS/MS) method for the determination of sucralose in reclaimed and drinking waters and its photo degradation in natural waters from South Florida [O] . Sudha Batchu, Natalia Quinete, Venkata R Panditi, 2013

机译：在线固相萃取液相色谱串联质谱法（SPE-LC-MS / MS）测定南佛罗里达州再生水和饮用水中的三氯蔗糖及其光降解
8. Method 557: Determination of Haloacetic Acids, Bromate, and Dalapon in Drinking Water by Ion chromatography Electrospray Ionization Tandem Mass Spectrometry (IC-ESI-MS/MS). Version 1.0. [R] . A. D. Zaffiro B. V. Pepich M. Zimmerman R. F. Jack R. W. Slingsby 2009

机译：方法557：通过离子色谱电喷雾电离串联质谱（IC-EsI-ms / ms）测定饮用水中的卤代乙酸，溴酸盐和Dalapon。版本1.0。

A New Fully Automated Online SPE/HPLC-MS/MS Method for the Determination of Phenoxycarboxylic Acids in Water

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