Simplification of Pharmaceutically Relevant Polymer Mass Spectra via Gas-Phase Ion/Ion Reactions with Carborane Anions

机译：通过与碳硼烷阴离子的气相离子反应通过气相离子反应简化药学相关的聚合物质谱

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When complicated polymer distributions are reacted with carborane anions, consecutive additions of the carborane anion is observed. This process is controlled and allowed to occur until the adducted polymer distribution is singly charged (viz., there is one adduct on the doubly charged polymer distribution, two adducts on the triply charged distribution, etc.). The singly charged adducted polymer distributions are activated by either a CID ramp or DDC activation resulting in each carborane anion removing one adducted cation.

机译：当复合聚合物分布与碳硼烷阴离子反应时，观察到碳硼烷阴离子的连续添加。控制并允许发生该方法，直到有机化的聚合物分布单独收取（viz，在双电荷的聚合物分布上有一个加合物，两个加合的有机电压分布等。通过CID斜坡或DDC活化激活单电加密的聚合物分布，得到每种碳硼烷阴离子去除一个有机阳离子。

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《ASMS Conference on Mass Spectrometry and Allied Topics》|2015年||共1页
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Carl A. Luongo; Stella K. Betancourt; Steven Cummings; Christopher A. Reed; Scott A. McLuckey;
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中图分类 TB994.5-53;
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1. Simplification of electrospray mass spectra of Polysorbate 80 via cation transfer to carborane anions [J] . Betancourt Stella K., Pilo Alice L., Bu Jiexun, Journal of mass spectrometry: JMS . 2016,第6期

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2. The Molar Mass Distribution of Polymer in Step-Growth Polymerization Influenced by Cyclization Reactions. The Simplified Case of Irreversible Reactions with Cyclizations Independent of the Ring Size~a [J] . Ryszard Szymanski Macromolecular theory and simulations . 2013,第6期

机译：环化反应影响聚合物在逐步增长聚合中的摩尔质量分布。与环大小无关的环化不可逆反应的简化情形
3. Ion/molecule reactions of o-carborane(12) and a method for identifying overlapped isotopic distributions in complex mass spectra [J] . Fiona H. Scholes, Richard J. S. Morrison, Colin L. Raston, International journal of mass spectrometry . 2000,第1a3期

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4. Simplification of Pharmaceutically Relevant Polymer Mass Spectra via Gas-Phase Ion/Ion Reactions with Carborane Anions [C] . Carl A. Luongo, Stella K. Betancourt, Steven Cummings, ASMS Conference on Mass Spectrometry and Allied Topics . 2015

机译：通过与碳硼烷阴离子的气相离子反应通过气相离子反应简化药学相关的聚合物质谱
5. Fundamentals and applications of charge inversion: Manipulations of ions during ion/ion reactions in the gas-phase for the analysis of biopharmaceutical-relevant molecules [D] . Hassell, Kerry M. 2010

机译：电荷反演的基本原理和应用：气相中离子/离子反应过程中离子的操纵，用于分析生物制药相关分子
6. Formation and reactions of negative ions relevant to chemical ionization mass spectrometry. I. Cl mass spectra of organic compounds produced by F− reactions [O] . T. O. Tiernan, C. Chang, C. C. Cheng 1980

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7. Formation and Reactions of Negative Ions Relevant to Chemical Ionization Mass Spectrometry. I. CI Mass Spectra of Organic Compounds Produced by F - Reactions [O] . T. O. Tiernan, C. Chang, C. C. Cheng 1980

机译：与化学电离质谱法相关的负离子的形成和反应。 I. F - 反应产生的有机化合物的CI质谱

Simplification of Pharmaceutically Relevant Polymer Mass Spectra via Gas-Phase Ion/Ion Reactions with Carborane Anions

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