PALLADIUM-CATALYZED STEREOSELECTIVE SYNTHESIS OF DEOXYGLYCOSIDES

机译：钯催化的脱氧糖苷的立体选择性合成

获取原文

页面导航

摘要
著录项
相似文献
相关主题

摘要

The chemical synthesis of complex carbohydrates generally involves the coupling of a fully protected glycosyl donor bearing a leaving group at its anomeric center, with a suitably protected glycosyl acceptor (R-OH). In many instances, these reactions lead to a mixture of two stereoisomers. To this day, the stereoselective synthesis of glycosides remains one of the biggest challenges in carbohydrate chemistry [1,2].

机译：复合碳水化合物的化学合成通常涉及携带在其异常中心的完全保护的糖基供体的偶联，其具有适当保护的糖基受体（R-OH）。在许多情况下，这些反应导致两个立体异构体的混合物。至今，糖苷的立体选择性合成仍然是碳水化合物化学中最大的挑战之一[1,2]。

著录项

来源
《International Carbohydrate Symposium》|2018年|832 p.|共1页
会议地点
作者
Abhijit Sau; Carlos Palo-Nieto; Ryan Williams;
展开▼
作者单位

展开▼
会议组织
原文格式 PDF
正文语种
中图分类碳水化合物、糖;
关键词

相似文献

外文文献
中文文献
专利

1. Copper Reactivity Can Be Tuned to Catalyze the Stereoselective Synthesis of 2-Deoxyglycosides from Glycals [J] . Palo-Nieto Carlos, Sau Abhijit, Jeanneret Robin, Organic letters . 2020,第5期

机译：可以调整铜反应性以催化来自族种的2-脱氧糖苷的立体选择性合成
2. Substrate-Controlled Direct alpha-Stereoselective Synthesis of Deoxyglycosides from Glycals Using B(C6F5)(3) as Catalyst [J] . Sau Abhijit, Palo-Nieto Carlos, Galan M. Carmen The Journal of Organic Chemistry . 2019,第5期

机译：使用B（C6F5）（3）作为催化剂，基质控制直接α-立体选择合成脱氧糖苷的脱氧糖苷
3. Stereoselective Synthesis of 2-Deoxyglycosides from Glycals by Visible-Light-Induced Photoacid Catalysis [J] . Zhao Gaoyuan, Wang Ting Angewandte Chemie . 2018,第21期

机译：通过可见光诱导的光酸催化从血糖中取代2-脱氧糖苷的立体选择性合成
4. PALLADIUM-CATALYZED STEREOSELECTIVE SYNTHESIS OF DEOXYGLYCOSIDES [C] . Abhijit Sau, Carlos Palo-Nieto, Ryan Williams International Carbohydrate Symposium . 2018

机译：钯催化的脱氧糖苷的立体选择性合成
5. A. Studies In The Allylic Substitution Chemistry Of Copper Hydride B. Stereoselective Silylcupration Of Conjugated Alkynes In Micellar Media C. Palladium-Catalyzed Synthesis Of 1,3-Butadienes and [3]-[6]Dendralenes D. Synthesis Of Small Molecule Underwater Adhesives Inspired By Mussels. [D] . Linstadt, Roscoe T. H. 2017

机译：A.氢化铜的烯丙基取代化学的研究B.共轭炔烃在胶束介质中的立体选择性甲硅烷基化C.钯催化的1,3-丁二烯和[3]-[6] Dendralenes的合成D.小分子水下胶粘剂的合成受贻贝启发。
6. Iridium-promoted deoxyglycoside synthesis: stereoselectivity and mechanistic insight [O] . Kumar Bhaskar Pal, Aoxin Guo, Mrinmoy Das, 2021

机译：铱促进的脱氧糖苷综合：立体选择性和机械洞察力
7. Palladium-Catalyzed Direct Stereoselective Synthesis of Deoxyglycosides from Glycals [O] . Abhijit Sau, Ryan Williams, Carlos Palo-Nieto, 2017

机译：钯 - 催化直接立体选择性合成甘油糖苷的脱氧糖苷

PALLADIUM-CATALYZED STEREOSELECTIVE SYNTHESIS OF DEOXYGLYCOSIDES

摘要

著录项

相似文献

相关主题

期刊订阅