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Polyacrylonitrile/Carbon nanotube Composite Fibers Toward Ultimate Reinforcement

机译:聚丙烯腈/碳纳米管复合纤维朝向最终增强

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Carbon nanotubes (CNTs) have been studied extensively due to their exceptional properties since 19911. CNTs have high modulus and high strength (~1 TPa and ~36 GPa, respectively)2,3. Recent studies suggest that polyacrylonitrile (PAN)/CNT composites are expected to be quite important4-11. PAN/CNT films and fibers4,9,11 with significant property improvements are being processed, indicating good interaction between PAN and CNTs, and the preliminary stabilization and carbonization studies on PAN/CNT composites also show promising results for processing next generation carbon fiber10. While CNT orientation as high as 0.98 has been achieved in the composite fiber11, theoretical studies suggest that in order to achieve the predicted modulus from CNTs, orientation factor approaching one is needed. To achieve ultra high SWNT orientation, PAN/SWNT composite fibers have been processed using gel spinning where draw ratios greater than 50 can be achieved. The results show nearly ideal SWNT orientation and nearly ideal modulus translation in the composite fiber. The properties of composite fibers spun by conventional dry-jet-wet spinning are also presented for a comparison.
机译:由于其自19911年以来,已经广泛地研究了碳纳米管(CNT).CNT分别具有高模量和高强度(分别为高强度(分别为〜36gA,36gA)2,3。最近的研究表明,聚丙烯腈(PAN)/ CNT复合材料预计非常重要的4-11。正在处理具有显着性质改进的PAN / CNT薄膜和纤维4,9,11,表明PAN和CNT之间的良好相互作用,对PAN / CNT复合材料的初步稳定和碳化研究还显示了加工下一代碳纤维10的有希望的结果。在复合光纤11中实现了高达0.98的CNT取向,但理论研究表明,为了实现来自CNT的预测模量,需要取向接近一个。为了实现超高SWNT取向,使用凝胶纺丝处理锅/ SWNT复合纤维,其中可以实现大于50的拉伸比。结果表明,复合纤维中几乎理想的SWNT取向和近乎理想的模量平移。还介绍了通过常规的干式湿纺纱纺丝的复合纤维的性质用于比较。

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