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ELECTRON-INTERMOLECULAR PHONON COUPLING IN κ-PHASE BEDT-TTF ORGANIC SUPERCONDUCTORS

机译:κ相BETT-TTF有机超导体中的电子分子间声子耦合

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First of all, we underline the success of QHLD method in describing BEDT-TTF_2I_3 structures and LP dynamics. Indeed, the crystals structures and the obsvervables connected to LP have been correctly reproduced for all the studied BEDT-TTF_2I_3 phases [1, 2], Key point to this success is the removal of RMA, allowing mixing of low-frequency intramolecular vibrations with the intermolecular phonons. The resulting description of low-frequency phonon dynamics is less simple, but by far more accurate. We have also demonstrated that both e-LP and e-MV couplings are essential to the SC properties of BEDT-TTF_2I_3 salts. The e-LP coupling is stronger, but the e-MV one is instrumental in increasing the average phonon frequency ω_ln. Therefore it appears that phonon mediated pairing is indeed able to account for the SC mechanism in BEDT-TTF_2I_3 salts. Other contributions, such as antiferromagnetic fluctuations, may become of importance in the highest T_c κ-phase salts. Work supported by the Italian Consiglio Nazionale delle Ricerche and by the Ministero dell'Universita e della Ricerca Scientifica e Tecnologica.
机译:首先,我们强调了QHLD方法在描述BEDT-TTF_2I_3结构和LP动力学方面的成功。的确,对于所有研究过的BEDT-TTF_2I_3相[1,2],已经正确地复制了与LP相连接的晶体结构和可观察物,成功的关键是去除了RMA,从而允许将低频分子内振动与振动相混合。分子间声子。低频声子动力学的最终结果描述不那么简单,但精确得多。我们还证明了e-LP和e-MV偶联对于BEDT-TTF_2I_3盐的SC性能至关重要。 e-LP耦合更强,但e-MV有助于提高平均声子频率ω_ln。因此看来,声子介导的配对确实能够解释BEDT-TTF_2I_3盐中的SC机制。在最高的T_cκ相盐中,其他作用(例如反铁磁波动)可能变得很重要。这项工作得到了意大利Consiglio Nazionale delle Ricerche以及大臣科学技术部的支持。

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