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Formation of Ni mono-germanosilicide on heavily B-doped epitaxial SiGe for ultra-shallow source/drain contacts

机译:在重掺杂B的外延SiGe上形成Ni-单锗硅化镍,用于超浅的源极/漏极接触

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摘要

The formation of Ni germanosilicides during solid-state interaction between Ni and heavily B-doped strained epitaxial Si_(1-x)Ge_x films with x=0.18, 0.32 and 0.37 is studied. No NiSi_2 is found in these samples even after annealing at 850 ℃, which can be compared to the formation of NiSi_2 at 750 ℃ on Si(100). Resistance and diffraction studies for the Si_(0.82)Ge_(0.18) sample indicate that NiSi_(0.82)Ge_(0.18) forms and the NiSi_(0.82)Ge_(0.18)/Si_(0.82)Ge_(0.18) structure is stable from 400 to 700 ℃. For the NiSi_(1-u)Ge_u formed in all Si_(1-x)Ge_x samples, where u can be different from x, a strong film texturing is observed. When the Ge fraction is increased from 18 at.% to 32-37 at.%, the morphological stability of the film is degraded and a substantial increase in sheet resistance occurs already at 600 ℃. The contact resistivity for the NiSi_(0.8)Ge_(0.2)/Si_(0.8)Ge_(0.2) interface formed at 550 ℃ is determined as 1.2xl0~(-7) Ωcm~2, which satisfies the ITRS contact resistivity requirement for the 70 nm technology node.
机译:研究了Ni与重掺杂B的应变外延Si_(1-x)Ge_x薄膜之间的固相相互作用过程中Ni锗硅化物的形成,x = 0.18、0.32和0.37。即使在850℃退火后,在这些样品中也没有发现NiSi_2,这可以与在Si(100)上750℃下形成NiSi_2进行比较。 Si_(0.82)Ge_(0.18)样品的电阻和衍射研究表明,NiSi_(0.82)Ge_(0.18)形成且NiSi_(0.82)Ge_(0.18)/ Si_(0.82)Ge_(0.18)结构在400℃下稳定到700℃。对于在所有Si_(1-x)Ge_x样品中形成的NiSi_(1-u)Ge_u,其中u可以不同于x,观察到了很强的薄膜纹理。当Ge含量从18at。%增加到32-37at。%时,薄膜的形貌稳定性下降,并且在600℃时薄层电阻已经显着增加。确定在550℃下形成的NiSi_(0.8)Ge_(0.2)/ Si_(0.8)Ge_(0.2)界面的接触电阻率为1.2xl0〜(-7)Ωcm〜2,满足ITRS要求。 70 nm技术节点。

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