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首页> 外文会议>Proceedings of the 12th international wool research conference.;vol. 2. >Thiol-functionalised Oligoglycidols for the Fixation of Creases in Wool Fabrics
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Thiol-functionalised Oligoglycidols for the Fixation of Creases in Wool Fabrics

机译：硫醇官能化聚缩水甘油用于固定羊毛织物中的折痕

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The physiologically safe thiol-functional polymers (thiomers) and oligomers are of interest for a variety of applications. Thiomers are yet used as drug delivery systems in medicine. Further potential applications of thiol-functional oligomers or polymers are the easy care finishing of textiles, achieving permanent creases in wool fabrics or permanent waving of human hair. Thiol-functionalised oligoglycidols with different molecular architectures were developed for the application onto wool fabrics. For the synthesis of linear oligoglycidols, acetal protected glycidols were used. After deprotection, the oligoglycidols were cross-linked with 3,3′-dithiodipropionic acid chloride. Reductive splitting of the disulfide bonds results in water-soluble, thiol-group containing oligoglycidols with molecular masses of 860-1200 g/mol in high yields. The thiol-functional oligoglycidols were applied to wool materials from a phosphate buffered solution of neutral to slightly basic pH. The wool was treated in the presence of a non-ionic surfactant at 40 °C for 20 to 60 minutes. Raman spectroscopy and crease angle measurements were used to prove the success of the treatment. The thiol-functional oligoglycidols were shown to penetrate into the wool fibre, to cleave the cystine bonds and to induce the rearrangement of the disulfide bridges. Thermal treatment completes the crease fixation. Thus, thiol-functional oligoglycidols were shown to achieve a very good crease fixation in wool fabrics.
机译：生理上安全的硫醇官能聚合物（硫醇）和低聚物对于各种应用都是令人关注的。硫醇还被用作药物中的药物递送系统。硫醇官能的低聚物或聚合物的其他潜在应用是纺织品的易于护理整理，从而在羊毛织物中实现永久性折痕或使人的头发永久性起伏。开发了具有不同分子结构的硫醇官能化寡糖苷脂，用于羊毛织物。为了合成线性寡糖醇，使用了乙缩醛保护的糖醇。脱保护后，将寡糖苷与3，3'-二硫代二丙酸酰氯交联。二硫键的还原裂解以高收率产生了分子量为860-1200 g / mol的水溶性，含硫醇基的寡糖苷。从中性至弱碱性的磷酸盐缓冲溶液将硫醇官能化的寡糖脂应用于羊毛材料。在非离子表面活性剂的存在下，将羊毛在40°C下处理20至60分钟。拉曼光谱法和折痕角测量被用来证明治疗的成功。巯基官能化的寡糖脂已显示出渗入羊毛纤维，裂解胱氨酸键并诱导二硫键的重排。热处理完成了折痕固定。因此，显示出在羊毛织物中具有硫醇官能的寡糖苷能实现非常好的折痕固定。

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