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Porosity-induced optical phonon engineering in III-V compounds

机译:III-V化合物中的孔隙度诱导的光子工程

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摘要

New possibilities for modifying the phonon spectra of III-V compounds are evidenced by micro-Raman analysis of porous layers prepared by electrochemical anodization of (111)A-oriented n-GaP substrates. In particular, a surface-related vibrational mode along with a porosity-induced decoupling between the longitudinal optical (LO) phonon and plasmon are observed. We prove that filling in the pores with other materials (aniline as a first approach) is a promising tool for controlling the surface phonon frequency.
机译:通过对(111)A取向n-GaP基板进行电化学阳极氧化制备的多孔层的显微拉曼分析,证明了修改III-V化合物声子光谱的新可能性。特别地,观察到与表面有关的振动模式,以及在纵向光学(LO)声子与等离激元之间的孔隙率引起的解耦。我们证明了用其他材料填充苯孔(作为第一方法的苯胺)是控制表面声子频率的有前途的工具。

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