首页> 美国卫生研究院文献>Acta Crystallographica Section E: Crystallographic Communications >catena-Polybis(1-ethyl-1H-imidazole-κN 3)cadmium-di-μ-chlorido-(1-ethyl-1H-imidazole-κN 3)cadmium-di-μ-chlorido-(1-ethyl-1H-imidazole-κN 3)cadmium-di-μ-chlorido-bis(1-ethyl-1H-imidazole-κN 3)cadmium

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catena-Polybis(1-ethyl-1H-imidazole-κN 3)cadmium-di-μ-chlorido-(1-ethyl-1H-imidazole-κN 3)cadmium-di-μ-chlorido-(1-ethyl-1H-imidazole-κN 3)cadmium-di-μ-chlorido-bis(1-ethyl-1H-imidazole-κN 3)cadmium

机译：阳离子多聚双（1-乙基-1H-咪唑-κN 3）镉-二-μ-氯代-（1-乙基-1H-咪唑-κN 3）镉-二-μ-氯代-（1-乙基-1H-咪唑-κN 3）镉-二-μ-氯代-双（1-乙基-1H-咪唑-κN 3）镉

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The asymmetric unit of the crystal structure of the title compound, [Cd2Cl4(C5H8N2)3]n, contains two Cd^II cations, three 1-ethyl-1H-imidazole ligands, and four Cl⁻ anions. The two Cd^II atoms have quite different coordination environments: one is octahedrally coordinated by four Cl atoms and two N atoms from two 1-ethyl-1H-imidazole ligands, and the second is in a severely distorted fivefold coordination by four Cl atoms and one N atom from a 1-ethyl-1H-imidazole ligand. Adjacent Cd^II cations are interconnected alternately by pairs of chloride bridges, generating an infinite step-like chain along the a axis. One ethyl group of the 1-ethyl-1H-imidazole ligand is disordered over two sets of sites with a 0.668 (13):0.332 (13) site-occupancy ratio.

机译：标题化合物[Cd2Cl4（C5H8N2）3] n的晶体结构不对称单元包含两个Cd ^{II 阳离子，三个1-乙基-1H-咪唑配体和四个Cl ^{− 阴离子。这两个Cd ^{II 原子具有完全不同的配位环境：一个由四个Cl原子和来自两个1-乙基-1H-咪唑配体的两个N原子八面体配位，第二个处于严重扭曲的五倍由1-乙基-1H-咪唑配体的四个Cl原子和一个N原子配位。相邻的Cd ^{II 阳离子通过成对的氯离子桥相互交替连接，沿a轴生成无限的阶梯状链。 1-乙基-1H-咪唑配体的一个乙基在两组位点上无序排列，位点占有率为0.668（13）：0.332（13）。}}}}

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期刊名称 Acta Crystallographica Section E: Crystallographic Communications
作者
Qian Xu; Run-Qiang Zhu;
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年(卷),期 2011(67),Pt 12
年度 2011
页码 m1850–m1851
总页数 12
原文格式 PDF
正文语种
中图分类生化遗传学;生化药理学;
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专利

1. Crystal structure of bis-(1-ethyl-1H-imidazole-κN3)(meso-tetra-mesitylporphyrinato-κ4N,N′,N′′,N′′′)iron(III) perchlorate chloro-benzene sesquisolvate [J] . Zhan N., Wang H., Li J. IUCrData . 2019,第5期

机译：双 - （1-乙基-1H-咪唑-κN3）的晶体结构（Meso-Tetra-Mesityhorphyrinato-κ4N，N'，N'，N''）铁（III）高氯酸氯苯均多溶血化物
2. catena-Poly[[bis(1-ethyl-1H-imidazole-κN3)cadmium]-di-μ-chlorido-[(1-ethyl-1H-imidazole-κN3)cadmium]-di-μ-chlorido-[(1-ethyl-1H-imidazole-κN3)cadmium]-di-μ-chlorido-[bis(1-ethyl-1H-imidazole-κN3)cadmium]] [J] . Xu Q., Zhu R.-Q. Acta Crystallographica Section E: Crystallographic Communications . 2011,第12期

机译：阳离子-[[双（1-乙基-1H-咪唑-κN3）镉]-二μ-氯代-[（（1-乙基-1H-咪唑-κN3）镉]-二μ-氯代-[（1 -乙基-1H-咪唑-κN3）镉]-二μ-氯代-[双（1-乙基-1H-咪唑-κN3）镉]]
3. catena-Poly[(dichloridocadmium)-di-μ-chlorido-[bis(morpholinium-κO)cadmium]-di-μ-chlorido] [J] . Dai J., Wang W. Acta Crystallographica Section E: Crystallographic Communications . 2011,第8期

机译：多链[（二氯代镉）-di-μ-氯代-[双（吗啉代-κO）镉]-di-μ-氯代]
4. catena-Polybis(1-ethyl-1H-imidazole-κN 3)copper(II)-μ-oxalato-κ4 O 1O 2:O 1′O 2′ [O] . Qian Xu 2011

机译：阳离子多聚双（1-乙基-1H-咪唑-κN 3）铜（II）-μ-草酸盐-κ4 Ø 1O 2：O 1.O 2
5. catena-Poly[[bis(1-ethyl-1H-imidazole-κN 3)cadmium]-di-μ-chlorido-[(1-ethyl-1H-imidazole-κN 3)cadmium]-di-μ-chlorido-[(1-ethyl-1H-imidazole-κN 3)cadmium]-di-μ-chlorido-[bis(1-ethyl-1H-imidazole-κN 3)cadmium]] [O] . Xu, Qian, Zhu, Run-Qiang 2011

机译：阳离子多聚[[双（1-乙基-1H-咪唑-κN 3）镉]-二-μ-氯代-[（1-乙基-1H-咪唑-κN 3）镉]-二-μ-氯代-[（1-乙基-1H-咪唑-κN 3）镉]-二-μ-氯代-[双（1-乙基-1H-咪唑-κN 3）[镉]]

catena-Polybis­(1-ethyl-1H-imidazole-κN 3)cadmium-di-μ-chlorido-(1-ethyl-1H-imidazole-κN 3)cadmium-di-μ-chlorido-(1-ethyl-1H-imidazole-κN 3)cadmium-di-μ-chlorido-bis­(1-ethyl-1H-imidazole-κN 3)cadmium

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catena-Polybis(1-ethyl-1H-imidazole-κN 3)cadmium-di-μ-chlorido-(1-ethyl-1H-imidazole-κN 3)cadmium-di-μ-chlorido-(1-ethyl-1H-imidazole-κN 3)cadmium-di-μ-chlorido-bis(1-ethyl-1H-imidazole-κN 3)cadmium