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Ligand Versatility in Supercrystal Formation

机译:超晶形成中的配体多功能性

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Supercrystals (SCs) offer the opportunity to integrate nanoparticles into current technologies without losing their unique and designable properties. In the past two decades, much research has been conducted, allowing the synthesis of differently shaped nanoparticles of various materials. Employing those building units, several methods have been developed enabling the preparation of an increasing number of different superstructures. In this review, an overview is given of the large versatility of surfactant molecules used for SC preparation. While SCs with uncharged organic ligands are by far the largest group, the use of charged or uncommon ligands allows the preparation of unique SCs and superlattices. Additionally, the influence of the ligands on the self-assembly and properties of the resulting SCs is highlighted.
机译:超晶(SC)提供了将纳米粒子集成到当前技术中的机会,而又不会失去其独特和可设计的特性。在过去的二十年中,进行了许多研究,从而可以合成各种材料的不同形状的纳米颗粒。利用这些建筑单元,已经开发了几种方法,能够制备越来越多的不同的上层建筑。在这篇综述中,概述了用于制备SC的表面活性剂分子的多功能性。迄今为止,带有不带电荷有机配体的超临界碳原子团是最大的组,但带电荷或不常见的配体的使用可以制备独特的超导原子和超晶格。另外,突出了配体对所得SC的自组装和性质的影响。

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