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Femtosecond laser micromachining of co-polymeric urethane materials

机译:共聚聚氨酯材料的飞秒激光微加工

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摘要

Single-step, contactless femtosecond laser micromachining of substrates to impart specific surface morphologies has been the focus of considerable recent work. This work has primarily focused on experimentation with metallic substrates, with fs-laser micromachining of polymeric materials being in its infancy. In the present work, we report on the fs-laser micromachining of urethane based, amorphous, non-block co-polymeric networks, where previously published literature has, to-date, solely discussed micromachining of homopolymeric substrates. The results of this work show that there exists regimes of micromachining where the imparted microstructure resembles those of selected irradiated homopolymers. Further inspection reveals the role of co-monomer added in determining the imparted microstructure through measurement of the material ionization threshold fluence, and incubation coefficient. Chemical and optical effects of co-monomer addition are also considered through XPS and UV-Vis spectroscopic analyses, respectively.
机译:单步,非接触式飞秒激光微机器以赋予特定表面形态的底物是最近的工作的重点。这项工作主要专注于金属衬底的实验,具有Comentic Materials的FS激光微加工在其婴儿期。在本作工作中,我们报告了基于氨基甲酸酯,非晶,非块共聚物网络的FS激光微机械线,其中先前公布的文献具有迄今为止,迄今为止讨论了均聚物衬底的微机械线。该工作的结果表明,存在微机械线的制度,其中赋予的微观结构类似于所选择的辐照均聚物。进一步检查揭示了通过测量材料电离阈值流量和孵育系数来确定赋予赋予微观结构的共聚单体的作用。通过XPS和UV-Vis光谱分析也考虑共聚单体添加的化学和光学效果。

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